A Synthetic Approach of New Trans-Substituted Hydroxylporphyrins

The synthesis of new trans A(2)B(2)-substituted porphyrins bearing oxygenic substituent (methoxy, acetoxy, hydroxy) at the periphery of the ring are described. All of the synthesized products were characterized by (1)H-N.M.R., (13)C-N.M.R., and H.R.M.S. Electrochemical studies revealed two one-elect...

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Detalles Bibliográficos
Autores principales: Daphnomili, Dimitra, Grammatikopoulou, Maria, Raptopoulou, Catherine, Charalambidis, George, Lazarides, Theodore, Coutsolelos, Athanasios G.
Formato: Texto
Lenguaje:English
Publicado: Hindawi Publishing Corporation 2010
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2901623/
https://www.ncbi.nlm.nih.gov/pubmed/20634981
http://dx.doi.org/10.1155/2010/307696
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author Daphnomili, Dimitra
Grammatikopoulou, Maria
Raptopoulou, Catherine
Charalambidis, George
Lazarides, Theodore
Coutsolelos, Athanasios G.
author_facet Daphnomili, Dimitra
Grammatikopoulou, Maria
Raptopoulou, Catherine
Charalambidis, George
Lazarides, Theodore
Coutsolelos, Athanasios G.
author_sort Daphnomili, Dimitra
collection PubMed
description The synthesis of new trans A(2)B(2)-substituted porphyrins bearing oxygenic substituent (methoxy, acetoxy, hydroxy) at the periphery of the ring are described. All of the synthesized products were characterized by (1)H-N.M.R., (13)C-N.M.R., and H.R.M.S. Electrochemical studies revealed two one-electron oxidations and two reductions. In addition, the X-ray structure of one methoxy-derivative was determined.
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spelling pubmed-29016232010-07-15 A Synthetic Approach of New Trans-Substituted Hydroxylporphyrins Daphnomili, Dimitra Grammatikopoulou, Maria Raptopoulou, Catherine Charalambidis, George Lazarides, Theodore Coutsolelos, Athanasios G. Bioinorg Chem Appl Research Article The synthesis of new trans A(2)B(2)-substituted porphyrins bearing oxygenic substituent (methoxy, acetoxy, hydroxy) at the periphery of the ring are described. All of the synthesized products were characterized by (1)H-N.M.R., (13)C-N.M.R., and H.R.M.S. Electrochemical studies revealed two one-electron oxidations and two reductions. In addition, the X-ray structure of one methoxy-derivative was determined. Hindawi Publishing Corporation 2010 2010-06-10 /pmc/articles/PMC2901623/ /pubmed/20634981 http://dx.doi.org/10.1155/2010/307696 Text en Copyright © 2010 Dimitra Daphnomili et al. https://creativecommons.org/licenses/by/3.0/ This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Article
Daphnomili, Dimitra
Grammatikopoulou, Maria
Raptopoulou, Catherine
Charalambidis, George
Lazarides, Theodore
Coutsolelos, Athanasios G.
A Synthetic Approach of New Trans-Substituted Hydroxylporphyrins
title A Synthetic Approach of New Trans-Substituted Hydroxylporphyrins
title_full A Synthetic Approach of New Trans-Substituted Hydroxylporphyrins
title_fullStr A Synthetic Approach of New Trans-Substituted Hydroxylporphyrins
title_full_unstemmed A Synthetic Approach of New Trans-Substituted Hydroxylporphyrins
title_short A Synthetic Approach of New Trans-Substituted Hydroxylporphyrins
title_sort synthetic approach of new trans-substituted hydroxylporphyrins
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2901623/
https://www.ncbi.nlm.nih.gov/pubmed/20634981
http://dx.doi.org/10.1155/2010/307696
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