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Synthesis and Structural Characterization of a Metal Cluster and a Coordination Polymer Based on the [Mn(6)(μ (4)-O)(2)](10+) Unit
A new 1-D coordination polymer {[Mn(6)O(2)(O(2)CMe)(10)(H(2)O)(4)]·2.5H(2)O}(∞) (1·2.5H(2)O)(∞) and the cluster [Mn(6)O(2)(O(2)(O(2)CPh)(10) (py)(2)(MeCN)(H(2)O)]·2MeCN (2·2MeCN) are reported. Both compounds were synthesized by room temperature reactions of [Mn(3)(μ (3)-O)(O(2)CR)(6)(L)(2)(L′)] (R =...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
Hindawi Publishing Corporation
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2902058/ https://www.ncbi.nlm.nih.gov/pubmed/20634987 http://dx.doi.org/10.1155/2010/367128 |