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In Search for Titanocene Complexes with Improved Cytotoxic Activity: Synthesis, X-Ray Structure, and Spectroscopic Study of Bis(η (5)-cyclopentadienyl)difluorotitanium(IV)

The 1 : 2 reaction of [Ti(η (5)-C(5)H(5))(2)Cl(2)] and AgF in CHCl(3)/H(2)O yielded the fluoro analog [Ti(η (5)-C(5)H(5))(2)F(2)] (1) in almost quantitative yield (C(5)H(5) is the cyclopentadienyl group). The coordination about the Ti(IV) atom formed by two fluoro ligands and the centroids of the cy...

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Detalles Bibliográficos
Autores principales:	Koleros, Elias, Stamatatos, Theocharis C., Psycharis, Vassilis, Raptopoulou, Catherine P., Perlepes, Spyros P., Klouras, Nikolaos
Formato:	Texto
Lenguaje:	English
Publicado:	Hindawi Publishing Corporation 2010
Materias:	Research Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2905951/ https://www.ncbi.nlm.nih.gov/pubmed/20689714 http://dx.doi.org/10.1155/2010/914580

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