NaFe(TeO(3))(2)

The hydro­thermally prepared title compound, sodium iron(III) bis­[trioxotellurate(IV)], is isotypic with its Ga(III) analogue and consists of corrugated layers with an overall composition of [FeTe(2)O(6)](−) together with Na(+) cations. The layers extend parallel to (001) and are made up of [Fe(2)O...

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Detalles Bibliográficos
Autores principales: Weil, Matthias, Stöger, Berthold
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914881/
https://www.ncbi.nlm.nih.gov/pubmed/21200453
http://dx.doi.org/10.1107/S1600536807065403
Descripción
Sumario:The hydro­thermally prepared title compound, sodium iron(III) bis­[trioxotellurate(IV)], is isotypic with its Ga(III) analogue and consists of corrugated layers with an overall composition of [FeTe(2)O(6)](−) together with Na(+) cations. The layers extend parallel to (001) and are made up of [Fe(2)O(10)] edge-shared octa­hedral dimers and TeO(3) trigonal pyramids sharing vertices. The Na(+) cations are located in the cavities of this arrangement and link adjacent [FeTe(2)O(6)](−) layers via distorted [NaO(8)] polyhedra.

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