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Octa­deca­bromidobis(dicarbido)deca­dysprosium, [Dy(10)Br(18)(C(2))(2)]

Single crystals of [Dy(10)Br(18)(C(2))(2)] were obtained during the reaction of DyBr(3) with dysprosium metal and graphite in a sealed tantalum container. In the crystal structure, the Dy atoms form dimers of edge-sharing octa­hedra, each encapsulating a C(2) unit. The metal atoms are surrounded by...

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Detalles Bibliográficos
Autores principales: Daub, Kathrin, Meyer, Gerd
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914882/
https://www.ncbi.nlm.nih.gov/pubmed/21200454
http://dx.doi.org/10.1107/S1600536807066111
Descripción
Sumario:Single crystals of [Dy(10)Br(18)(C(2))(2)] were obtained during the reaction of DyBr(3) with dysprosium metal and graphite in a sealed tantalum container. In the crystal structure, the Dy atoms form dimers of edge-sharing octa­hedra, each encapsulating a C(2) unit. The metal atoms are surrounded by Br atoms above the cluster edges and vertices, respectively. The dimers are connected to each other by Br atoms, leading to a three-dimensional network. [Dy(10)Br(18)(C(2))(2)] is isotypic with its iodido analogue [Dy(10)I(18)(C(2))(2)].