Cargando…
Octadecabromidobis(dicarbido)decadysprosium, [Dy(10)Br(18)(C(2))(2)]
Single crystals of [Dy(10)Br(18)(C(2))(2)] were obtained during the reaction of DyBr(3) with dysprosium metal and graphite in a sealed tantalum container. In the crystal structure, the Dy atoms form dimers of edge-sharing octahedra, each encapsulating a C(2) unit. The metal atoms are surrounded by...
Autores principales: | , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914882/ https://www.ncbi.nlm.nih.gov/pubmed/21200454 http://dx.doi.org/10.1107/S1600536807066111 |
Sumario: | Single crystals of [Dy(10)Br(18)(C(2))(2)] were obtained during the reaction of DyBr(3) with dysprosium metal and graphite in a sealed tantalum container. In the crystal structure, the Dy atoms form dimers of edge-sharing octahedra, each encapsulating a C(2) unit. The metal atoms are surrounded by Br atoms above the cluster edges and vertices, respectively. The dimers are connected to each other by Br atoms, leading to a three-dimensional network. [Dy(10)Br(18)(C(2))(2)] is isotypic with its iodido analogue [Dy(10)I(18)(C(2))(2)]. |
---|