Octa­deca­bromidobis(dicarbido)deca­dysprosium, [Dy(10)Br(18)(C(2))(2)]

Single crystals of [Dy(10)Br(18)(C(2))(2)] were obtained during the reaction of DyBr(3) with dysprosium metal and graphite in a sealed tantalum container. In the crystal structure, the Dy atoms form dimers of edge-sharing octa­hedra, each encapsulating a C(2) unit. The metal atoms are surrounded by...

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Detalles Bibliográficos
Autores principales: Daub, Kathrin, Meyer, Gerd
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914882/
https://www.ncbi.nlm.nih.gov/pubmed/21200454
http://dx.doi.org/10.1107/S1600536807066111
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author Daub, Kathrin
Meyer, Gerd
author_facet Daub, Kathrin
Meyer, Gerd
author_sort Daub, Kathrin
collection PubMed
description Single crystals of [Dy(10)Br(18)(C(2))(2)] were obtained during the reaction of DyBr(3) with dysprosium metal and graphite in a sealed tantalum container. In the crystal structure, the Dy atoms form dimers of edge-sharing octa­hedra, each encapsulating a C(2) unit. The metal atoms are surrounded by Br atoms above the cluster edges and vertices, respectively. The dimers are connected to each other by Br atoms, leading to a three-dimensional network. [Dy(10)Br(18)(C(2))(2)] is isotypic with its iodido analogue [Dy(10)I(18)(C(2))(2)].
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spelling pubmed-29148822010-12-30 Octa­deca­bromidobis(dicarbido)deca­dysprosium, [Dy(10)Br(18)(C(2))(2)] Daub, Kathrin Meyer, Gerd Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Single crystals of [Dy(10)Br(18)(C(2))(2)] were obtained during the reaction of DyBr(3) with dysprosium metal and graphite in a sealed tantalum container. In the crystal structure, the Dy atoms form dimers of edge-sharing octa­hedra, each encapsulating a C(2) unit. The metal atoms are surrounded by Br atoms above the cluster edges and vertices, respectively. The dimers are connected to each other by Br atoms, leading to a three-dimensional network. [Dy(10)Br(18)(C(2))(2)] is isotypic with its iodido analogue [Dy(10)I(18)(C(2))(2)]. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2914882/ /pubmed/21200454 http://dx.doi.org/10.1107/S1600536807066111 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Inorganic Papers
Daub, Kathrin
Meyer, Gerd
Octa­deca­bromidobis(dicarbido)deca­dysprosium, [Dy(10)Br(18)(C(2))(2)]
title Octa­deca­bromidobis(dicarbido)deca­dysprosium, [Dy(10)Br(18)(C(2))(2)]
title_full Octa­deca­bromidobis(dicarbido)deca­dysprosium, [Dy(10)Br(18)(C(2))(2)]
title_fullStr Octa­deca­bromidobis(dicarbido)deca­dysprosium, [Dy(10)Br(18)(C(2))(2)]
title_full_unstemmed Octa­deca­bromidobis(dicarbido)deca­dysprosium, [Dy(10)Br(18)(C(2))(2)]
title_short Octa­deca­bromidobis(dicarbido)deca­dysprosium, [Dy(10)Br(18)(C(2))(2)]
title_sort octa­deca­bromidobis(dicarbido)deca­dysprosium, [dy(10)br(18)(c(2))(2)]
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914882/
https://www.ncbi.nlm.nih.gov/pubmed/21200454
http://dx.doi.org/10.1107/S1600536807066111
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