Reinvestigation of tris­odium dihydroxido­tetra­oxidoneptunate(VII) dihydrate

The title compound, Na(3)[NpO(4)(OH)(2)]·2H(2)O, contains distorted tetra­gonal–bipyramidal centrosymmetric [NpO(4)(OH)(2)](3−) complex anions. The Np—O distances are 1.8975 (7) and 1.8891 (7) Å in the NpO(4) group and 2.3451 (7) Å to the OH group. Both Na atoms (one in a general position, the secon...

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Detalles Bibliográficos
Autores principales: Grigoriev, Mikhail S., Krot, Nikolai N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914884/
https://www.ncbi.nlm.nih.gov/pubmed/21200456
http://dx.doi.org/10.1107/S1600536807066962
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author Grigoriev, Mikhail S.
Krot, Nikolai N.
author_facet Grigoriev, Mikhail S.
Krot, Nikolai N.
author_sort Grigoriev, Mikhail S.
collection PubMed
description The title compound, Na(3)[NpO(4)(OH)(2)]·2H(2)O, contains distorted tetra­gonal–bipyramidal centrosymmetric [NpO(4)(OH)(2)](3−) complex anions. The Np—O distances are 1.8975 (7) and 1.8891 (7) Å in the NpO(4) group and 2.3451 (7) Å to the OH group. Both Na atoms (one in a general position, the second in a special position on an inversion centre) have a distorted octahedral oxygen environment.
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spelling pubmed-29148842010-12-30 Reinvestigation of tris­odium dihydroxido­tetra­oxidoneptunate(VII) dihydrate Grigoriev, Mikhail S. Krot, Nikolai N. Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, Na(3)[NpO(4)(OH)(2)]·2H(2)O, contains distorted tetra­gonal–bipyramidal centrosymmetric [NpO(4)(OH)(2)](3−) complex anions. The Np—O distances are 1.8975 (7) and 1.8891 (7) Å in the NpO(4) group and 2.3451 (7) Å to the OH group. Both Na atoms (one in a general position, the second in a special position on an inversion centre) have a distorted octahedral oxygen environment. International Union of Crystallography 2007-12-21 /pmc/articles/PMC2914884/ /pubmed/21200456 http://dx.doi.org/10.1107/S1600536807066962 Text en © Grigoriev and Krot 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Grigoriev, Mikhail S.
Krot, Nikolai N.
Reinvestigation of tris­odium dihydroxido­tetra­oxidoneptunate(VII) dihydrate
title Reinvestigation of tris­odium dihydroxido­tetra­oxidoneptunate(VII) dihydrate
title_full Reinvestigation of tris­odium dihydroxido­tetra­oxidoneptunate(VII) dihydrate
title_fullStr Reinvestigation of tris­odium dihydroxido­tetra­oxidoneptunate(VII) dihydrate
title_full_unstemmed Reinvestigation of tris­odium dihydroxido­tetra­oxidoneptunate(VII) dihydrate
title_short Reinvestigation of tris­odium dihydroxido­tetra­oxidoneptunate(VII) dihydrate
title_sort reinvestigation of tris­odium dihydroxido­tetra­oxidoneptunate(vii) dihydrate
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914884/
https://www.ncbi.nlm.nih.gov/pubmed/21200456
http://dx.doi.org/10.1107/S1600536807066962
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AT krotnikolain reinvestigationoftrisodiumdihydroxidotetraoxidoneptunateviidihydrate

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