μ-Oxido-bis­{chlorido[tris­(2-pyridylmeth­yl)amine]chromium(III)} bis(hexafluoridophosphate)

The title compound, [Cr(2)Cl(2)O(C(18)H(18)N(4))(2)](PF(6))(2), is isostructural with the V(III) analogue. Each Cr(III) atom is chelated by the tetra­dentate tris­(2-pyridylmeth­yl)amine ligand via four N atoms, and further coordinated by one Cl atom and one bridging O atom, giving a slightly distor...

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Detalles Bibliográficos
Autores principales: Li, Sheng, Wang, Shou-Bin, Zhang, Fu-Li, Tang, Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914886/
https://www.ncbi.nlm.nih.gov/pubmed/21200546
http://dx.doi.org/10.1107/S1600536807061296
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author Li, Sheng
Wang, Shou-Bin
Zhang, Fu-Li
Tang, Kun
author_facet Li, Sheng
Wang, Shou-Bin
Zhang, Fu-Li
Tang, Kun
author_sort Li, Sheng
collection PubMed
description The title compound, [Cr(2)Cl(2)O(C(18)H(18)N(4))(2)](PF(6))(2), is isostructural with the V(III) analogue. Each Cr(III) atom is chelated by the tetra­dentate tris­(2-pyridylmeth­yl)amine ligand via four N atoms, and further coordinated by one Cl atom and one bridging O atom, giving a slightly distorted octa­hedral coordination geometry. The dinuclear complex is centrosymmetric, with the bridging O atom lying on a centre of inversion.
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spelling pubmed-29148862010-12-30 μ-Oxido-bis­{chlorido[tris­(2-pyridylmeth­yl)amine]chromium(III)} bis(hexafluoridophosphate) Li, Sheng Wang, Shou-Bin Zhang, Fu-Li Tang, Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cr(2)Cl(2)O(C(18)H(18)N(4))(2)](PF(6))(2), is isostructural with the V(III) analogue. Each Cr(III) atom is chelated by the tetra­dentate tris­(2-pyridylmeth­yl)amine ligand via four N atoms, and further coordinated by one Cl atom and one bridging O atom, giving a slightly distorted octa­hedral coordination geometry. The dinuclear complex is centrosymmetric, with the bridging O atom lying on a centre of inversion. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914886/ /pubmed/21200546 http://dx.doi.org/10.1107/S1600536807061296 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Li, Sheng
Wang, Shou-Bin
Zhang, Fu-Li
Tang, Kun
μ-Oxido-bis­{chlorido[tris­(2-pyridylmeth­yl)amine]chromium(III)} bis(hexafluoridophosphate)
title μ-Oxido-bis­{chlorido[tris­(2-pyridylmeth­yl)amine]chromium(III)} bis(hexafluoridophosphate)
title_full μ-Oxido-bis­{chlorido[tris­(2-pyridylmeth­yl)amine]chromium(III)} bis(hexafluoridophosphate)
title_fullStr μ-Oxido-bis­{chlorido[tris­(2-pyridylmeth­yl)amine]chromium(III)} bis(hexafluoridophosphate)
title_full_unstemmed μ-Oxido-bis­{chlorido[tris­(2-pyridylmeth­yl)amine]chromium(III)} bis(hexafluoridophosphate)
title_short μ-Oxido-bis­{chlorido[tris­(2-pyridylmeth­yl)amine]chromium(III)} bis(hexafluoridophosphate)
title_sort μ-oxido-bis­{chlorido[tris­(2-pyridylmeth­yl)amine]chromium(iii)} bis(hexafluoridophosphate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914886/
https://www.ncbi.nlm.nih.gov/pubmed/21200546
http://dx.doi.org/10.1107/S1600536807061296
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