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μ-4,4′-Diazenediyldiphthalato-κ(2) O (2):O (2′)-bis[pentaaquamanganese(II)] tetrahydrate
The dinuclear complex in the title compound, [Mn(2)(C(16)H(6)N(2)O(8))(H(2)O)(10)]·4H(2)O, lies on an inversion center. Two delocalized carboxylate groups are each connected in a monodentate fashion to two similar pentaaquamanganese units, whereas the other two localized carboxylate groups are u...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2007
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914887/ https://www.ncbi.nlm.nih.gov/pubmed/21200604 http://dx.doi.org/10.1107/S1600536807061314 |
| _version_ | 1782184808375386112 |
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| author | Bai, Jian-Wei Wang, Jun Hou, Yang Zhao, Bao-Zhong Fu, Qiang |
| author_facet | Bai, Jian-Wei Wang, Jun Hou, Yang Zhao, Bao-Zhong Fu, Qiang |
| author_sort | Bai, Jian-Wei |
| collection | PubMed |
| description | The dinuclear complex in the title compound, [Mn(2)(C(16)H(6)N(2)O(8))(H(2)O)(10)]·4H(2)O, lies on an inversion center. Two delocalized carboxylate groups are each connected in a monodentate fashion to two similar pentaaquamanganese units, whereas the other two localized carboxylate groups are uncoordinated. The metal ion has octahedral coordination, with the O atom of a carboxylate group and three coordinated water molecules forming the equatorial plane [Mn—O(COO) = 2.143 (4) Å] and two water molecules occupying the axial positions. The architecture is further consolidated by extensive hydrogen bonds for which coordinated water molecules serve as donors or acceptors. |
| format | Text |
| id | pubmed-2914887 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29148872010-12-30 μ-4,4′-Diazenediyldiphthalato-κ(2) O (2):O (2′)-bis[pentaaquamanganese(II)] tetrahydrate Bai, Jian-Wei Wang, Jun Hou, Yang Zhao, Bao-Zhong Fu, Qiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear complex in the title compound, [Mn(2)(C(16)H(6)N(2)O(8))(H(2)O)(10)]·4H(2)O, lies on an inversion center. Two delocalized carboxylate groups are each connected in a monodentate fashion to two similar pentaaquamanganese units, whereas the other two localized carboxylate groups are uncoordinated. The metal ion has octahedral coordination, with the O atom of a carboxylate group and three coordinated water molecules forming the equatorial plane [Mn—O(COO) = 2.143 (4) Å] and two water molecules occupying the axial positions. The architecture is further consolidated by extensive hydrogen bonds for which coordinated water molecules serve as donors or acceptors. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914887/ /pubmed/21200604 http://dx.doi.org/10.1107/S1600536807061314 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
| spellingShingle | Metal-Organic Papers Bai, Jian-Wei Wang, Jun Hou, Yang Zhao, Bao-Zhong Fu, Qiang μ-4,4′-Diazenediyldiphthalato-κ(2) O (2):O (2′)-bis[pentaaquamanganese(II)] tetrahydrate |
| title | μ-4,4′-Diazenediyldiphthalato-κ(2)
O
(2):O
(2′)-bis[pentaaquamanganese(II)] tetrahydrate |
| title_full | μ-4,4′-Diazenediyldiphthalato-κ(2)
O
(2):O
(2′)-bis[pentaaquamanganese(II)] tetrahydrate |
| title_fullStr | μ-4,4′-Diazenediyldiphthalato-κ(2)
O
(2):O
(2′)-bis[pentaaquamanganese(II)] tetrahydrate |
| title_full_unstemmed | μ-4,4′-Diazenediyldiphthalato-κ(2)
O
(2):O
(2′)-bis[pentaaquamanganese(II)] tetrahydrate |
| title_short | μ-4,4′-Diazenediyldiphthalato-κ(2)
O
(2):O
(2′)-bis[pentaaquamanganese(II)] tetrahydrate |
| title_sort | μ-4,4′-diazenediyldiphthalato-κ(2)
o
(2):o
(2′)-bis[pentaaquamanganese(ii)] tetrahydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914887/ https://www.ncbi.nlm.nih.gov/pubmed/21200604 http://dx.doi.org/10.1107/S1600536807061314 |
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