Poly[di-μ(3)-azido-μ(2)-4,4′-bipyridine-dicopper(I)]

In the crystal structure of the title compound, [Cu(2)(N(3))(2)(C(10)H(8)N(2))](n), each Cu(I) atom is coordinated by two symmetry-related azide anions and 4,4′-bipyridine (bipy) ligands in a strongly distorted tetra­hedral geometry. The Cu atom and the azide anion occupy general positions while the...

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Detalles Bibliográficos
Autores principales: Liu, Fu-Chen, Ouyang, Jie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914889/
https://www.ncbi.nlm.nih.gov/pubmed/21200631
http://dx.doi.org/10.1107/S1600536807061569
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author Liu, Fu-Chen
Ouyang, Jie
author_facet Liu, Fu-Chen
Ouyang, Jie
author_sort Liu, Fu-Chen
collection PubMed
description In the crystal structure of the title compound, [Cu(2)(N(3))(2)(C(10)H(8)N(2))](n), each Cu(I) atom is coordinated by two symmetry-related azide anions and 4,4′-bipyridine (bipy) ligands in a strongly distorted tetra­hedral geometry. The Cu atom and the azide anion occupy general positions while the bipy mol­ecule is located on a centre of inversion. Each two symmetry-related copper(I) cations and two symmetry-related azide anions form dimers, which are additionally connected by the anions into layers. These layers are linked by the 4,4′-bipyridine ligands into a three-dimensional coordination network.
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spelling pubmed-29148892010-12-30 Poly[di-μ(3)-azido-μ(2)-4,4′-bipyridine-dicopper(I)] Liu, Fu-Chen Ouyang, Jie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Cu(2)(N(3))(2)(C(10)H(8)N(2))](n), each Cu(I) atom is coordinated by two symmetry-related azide anions and 4,4′-bipyridine (bipy) ligands in a strongly distorted tetra­hedral geometry. The Cu atom and the azide anion occupy general positions while the bipy mol­ecule is located on a centre of inversion. Each two symmetry-related copper(I) cations and two symmetry-related azide anions form dimers, which are additionally connected by the anions into layers. These layers are linked by the 4,4′-bipyridine ligands into a three-dimensional coordination network. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914889/ /pubmed/21200631 http://dx.doi.org/10.1107/S1600536807061569 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Liu, Fu-Chen
Ouyang, Jie
Poly[di-μ(3)-azido-μ(2)-4,4′-bipyridine-dicopper(I)]
title Poly[di-μ(3)-azido-μ(2)-4,4′-bipyridine-dicopper(I)]
title_full Poly[di-μ(3)-azido-μ(2)-4,4′-bipyridine-dicopper(I)]
title_fullStr Poly[di-μ(3)-azido-μ(2)-4,4′-bipyridine-dicopper(I)]
title_full_unstemmed Poly[di-μ(3)-azido-μ(2)-4,4′-bipyridine-dicopper(I)]
title_short Poly[di-μ(3)-azido-μ(2)-4,4′-bipyridine-dicopper(I)]
title_sort poly[di-μ(3)-azido-μ(2)-4,4′-bipyridine-dicopper(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914889/
https://www.ncbi.nlm.nih.gov/pubmed/21200631
http://dx.doi.org/10.1107/S1600536807061569
work_keys_str_mv AT liufuchen polydim3azidom244bipyridinedicopperi
AT ouyangjie polydim3azidom244bipyridinedicopperi

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