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(2R*,3R*,4aS*,6aR*,11aS*,11bS*)-Methyl 2-acetoxy-11b-hydroxy-3,7-dimethyl-1,2,3,4,4a,5,6,6a,7,11,11a,11b-dodecahydrophenanthro[3,2-b]furan-3-carboxylate
In the title compound, C(22)H(30)O(6), the conformation of the molecule is dictated by an intramolecular C—H⋯O contact. The crystal structure is stabilized via intermolecular C—H⋯O, O—H⋯O and C—H⋯π contacts.
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2007
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914899/ https://www.ncbi.nlm.nih.gov/pubmed/21200967 http://dx.doi.org/10.1107/S1600536807061934 |
| _version_ | 1782184811279941632 |
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| author | Prathap, S. J. Rajanna, L. N. Sheetal, C. Seetharam, Y. N. Row, T. N. Guru |
| author_facet | Prathap, S. J. Rajanna, L. N. Sheetal, C. Seetharam, Y. N. Row, T. N. Guru |
| author_sort | Prathap, S. J. |
| collection | PubMed |
| description | In the title compound, C(22)H(30)O(6), the conformation of the molecule is dictated by an intramolecular C—H⋯O contact. The crystal structure is stabilized via intermolecular C—H⋯O, O—H⋯O and C—H⋯π contacts. |
| format | Text |
| id | pubmed-2914899 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29148992010-12-30 (2R*,3R*,4aS*,6aR*,11aS*,11bS*)-Methyl 2-acetoxy-11b-hydroxy-3,7-dimethyl-1,2,3,4,4a,5,6,6a,7,11,11a,11b-dodecahydrophenanthro[3,2-b]furan-3-carboxylate Prathap, S. J. Rajanna, L. N. Sheetal, C. Seetharam, Y. N. Row, T. N. Guru Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(30)O(6), the conformation of the molecule is dictated by an intramolecular C—H⋯O contact. The crystal structure is stabilized via intermolecular C—H⋯O, O—H⋯O and C—H⋯π contacts. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914899/ /pubmed/21200967 http://dx.doi.org/10.1107/S1600536807061934 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
| spellingShingle | Organic Papers Prathap, S. J. Rajanna, L. N. Sheetal, C. Seetharam, Y. N. Row, T. N. Guru (2R*,3R*,4aS*,6aR*,11aS*,11bS*)-Methyl 2-acetoxy-11b-hydroxy-3,7-dimethyl-1,2,3,4,4a,5,6,6a,7,11,11a,11b-dodecahydrophenanthro[3,2-b]furan-3-carboxylate |
| title | (2R*,3R*,4aS*,6aR*,11aS*,11bS*)-Methyl 2-acetoxy-11b-hydroxy-3,7-dimethyl-1,2,3,4,4a,5,6,6a,7,11,11a,11b-dodecahydrophenanthro[3,2-b]furan-3-carboxylate |
| title_full | (2R*,3R*,4aS*,6aR*,11aS*,11bS*)-Methyl 2-acetoxy-11b-hydroxy-3,7-dimethyl-1,2,3,4,4a,5,6,6a,7,11,11a,11b-dodecahydrophenanthro[3,2-b]furan-3-carboxylate |
| title_fullStr | (2R*,3R*,4aS*,6aR*,11aS*,11bS*)-Methyl 2-acetoxy-11b-hydroxy-3,7-dimethyl-1,2,3,4,4a,5,6,6a,7,11,11a,11b-dodecahydrophenanthro[3,2-b]furan-3-carboxylate |
| title_full_unstemmed | (2R*,3R*,4aS*,6aR*,11aS*,11bS*)-Methyl 2-acetoxy-11b-hydroxy-3,7-dimethyl-1,2,3,4,4a,5,6,6a,7,11,11a,11b-dodecahydrophenanthro[3,2-b]furan-3-carboxylate |
| title_short | (2R*,3R*,4aS*,6aR*,11aS*,11bS*)-Methyl 2-acetoxy-11b-hydroxy-3,7-dimethyl-1,2,3,4,4a,5,6,6a,7,11,11a,11b-dodecahydrophenanthro[3,2-b]furan-3-carboxylate |
| title_sort | (2r*,3r*,4as*,6ar*,11as*,11bs*)-methyl 2-acetoxy-11b-hydroxy-3,7-dimethyl-1,2,3,4,4a,5,6,6a,7,11,11a,11b-dodecahydrophenanthro[3,2-b]furan-3-carboxylate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914899/ https://www.ncbi.nlm.nih.gov/pubmed/21200967 http://dx.doi.org/10.1107/S1600536807061934 |
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