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(Di-2-pyridyl sulfide-κ(2) N,N′)diiodidozinc(II)
The title compound, [ZnI(2)(C(10)H(8)N(2)S)], contains a six-membered chelate ring adopting a boat conformation in which the Zn atom is coordinated by two iodide ions and by the two pyridyl N atoms of a single di-2-pyridyl sulfide ligand within a slightly distorted tetrahedron. The Zn, S and I atom...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2007
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914904/ https://www.ncbi.nlm.nih.gov/pubmed/21200469 http://dx.doi.org/10.1107/S1600536807062502 |
| _version_ | 1782184812481609728 |
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| author | Wriedt, Mario Jess, Inke Näther, Christian |
| author_facet | Wriedt, Mario Jess, Inke Näther, Christian |
| author_sort | Wriedt, Mario |
| collection | PubMed |
| description | The title compound, [ZnI(2)(C(10)H(8)N(2)S)], contains a six-membered chelate ring adopting a boat conformation in which the Zn atom is coordinated by two iodide ions and by the two pyridyl N atoms of a single di-2-pyridyl sulfide ligand within a slightly distorted tetrahedron. The Zn, S and I atoms are located on a crystallographic mirror plane. As usual for this type of complex, the sulfide group does not participate in zinc coordination. The dihedral angle between the two pyridine rings is 60.1 (1)°. |
| format | Text |
| id | pubmed-2914904 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29149042010-12-30 (Di-2-pyridyl sulfide-κ(2) N,N′)diiodidozinc(II) Wriedt, Mario Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [ZnI(2)(C(10)H(8)N(2)S)], contains a six-membered chelate ring adopting a boat conformation in which the Zn atom is coordinated by two iodide ions and by the two pyridyl N atoms of a single di-2-pyridyl sulfide ligand within a slightly distorted tetrahedron. The Zn, S and I atoms are located on a crystallographic mirror plane. As usual for this type of complex, the sulfide group does not participate in zinc coordination. The dihedral angle between the two pyridine rings is 60.1 (1)°. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914904/ /pubmed/21200469 http://dx.doi.org/10.1107/S1600536807062502 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
| spellingShingle | Metal-Organic Papers Wriedt, Mario Jess, Inke Näther, Christian (Di-2-pyridyl sulfide-κ(2) N,N′)diiodidozinc(II) |
| title | (Di-2-pyridyl sulfide-κ(2)
N,N′)diiodidozinc(II) |
| title_full | (Di-2-pyridyl sulfide-κ(2)
N,N′)diiodidozinc(II) |
| title_fullStr | (Di-2-pyridyl sulfide-κ(2)
N,N′)diiodidozinc(II) |
| title_full_unstemmed | (Di-2-pyridyl sulfide-κ(2)
N,N′)diiodidozinc(II) |
| title_short | (Di-2-pyridyl sulfide-κ(2)
N,N′)diiodidozinc(II) |
| title_sort | (di-2-pyridyl sulfide-κ(2)
n,n′)diiodidozinc(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914904/ https://www.ncbi.nlm.nih.gov/pubmed/21200469 http://dx.doi.org/10.1107/S1600536807062502 |
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