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Tetrakis(μ-anthracene-9-carboxylato)bis[(anthracene-9-carboxylato)(2,2′-bipyridyl)lanthanum(III)]
The title complex, [La(2)(C(15)H(9)O(2))(6)(C(10)H(8)N(2))(2)], has a centrosymmetric binuclear cage structure in which two La(III )atoms are both nine-coordinated and bridged by four anthracene-9-carboxylate ligands, with an La⋯La separation of 4.0880 (4) Å. The remaining coordination sites are oc...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914908/ https://www.ncbi.nlm.nih.gov/pubmed/21200503 http://dx.doi.org/10.1107/S1600536807062241 |
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author | Liu, Chun-Sen Yan, Li-Fen Chang, Ze Wang, Jun-Jie |
author_facet | Liu, Chun-Sen Yan, Li-Fen Chang, Ze Wang, Jun-Jie |
author_sort | Liu, Chun-Sen |
collection | PubMed |
description | The title complex, [La(2)(C(15)H(9)O(2))(6)(C(10)H(8)N(2))(2)], has a centrosymmetric binuclear cage structure in which two La(III )atoms are both nine-coordinated and bridged by four anthracene-9-carboxylate ligands, with an La⋯La separation of 4.0880 (4) Å. The remaining coordination sites are occupied by two N atoms of a 2,2′-bipyridine (bipy) and two O atoms of an anthracene-9-carboxylate ligand. The six anthracene-9-carboxylate groups coordinate each La(III )atom in three different ways. Adjacent discrete dinuclear units are arranged into a one-dimensional chain along the [111] direction by intermolecular π–π stacking interactions, with a centroid–centroid separation of 3.704 (7) Å. |
format | Text |
id | pubmed-2914908 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29149082010-12-30 Tetrakis(μ-anthracene-9-carboxylato)bis[(anthracene-9-carboxylato)(2,2′-bipyridyl)lanthanum(III)] Liu, Chun-Sen Yan, Li-Fen Chang, Ze Wang, Jun-Jie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [La(2)(C(15)H(9)O(2))(6)(C(10)H(8)N(2))(2)], has a centrosymmetric binuclear cage structure in which two La(III )atoms are both nine-coordinated and bridged by four anthracene-9-carboxylate ligands, with an La⋯La separation of 4.0880 (4) Å. The remaining coordination sites are occupied by two N atoms of a 2,2′-bipyridine (bipy) and two O atoms of an anthracene-9-carboxylate ligand. The six anthracene-9-carboxylate groups coordinate each La(III )atom in three different ways. Adjacent discrete dinuclear units are arranged into a one-dimensional chain along the [111] direction by intermolecular π–π stacking interactions, with a centroid–centroid separation of 3.704 (7) Å. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914908/ /pubmed/21200503 http://dx.doi.org/10.1107/S1600536807062241 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Liu, Chun-Sen Yan, Li-Fen Chang, Ze Wang, Jun-Jie Tetrakis(μ-anthracene-9-carboxylato)bis[(anthracene-9-carboxylato)(2,2′-bipyridyl)lanthanum(III)] |
title | Tetrakis(μ-anthracene-9-carboxylato)bis[(anthracene-9-carboxylato)(2,2′-bipyridyl)lanthanum(III)] |
title_full | Tetrakis(μ-anthracene-9-carboxylato)bis[(anthracene-9-carboxylato)(2,2′-bipyridyl)lanthanum(III)] |
title_fullStr | Tetrakis(μ-anthracene-9-carboxylato)bis[(anthracene-9-carboxylato)(2,2′-bipyridyl)lanthanum(III)] |
title_full_unstemmed | Tetrakis(μ-anthracene-9-carboxylato)bis[(anthracene-9-carboxylato)(2,2′-bipyridyl)lanthanum(III)] |
title_short | Tetrakis(μ-anthracene-9-carboxylato)bis[(anthracene-9-carboxylato)(2,2′-bipyridyl)lanthanum(III)] |
title_sort | tetrakis(μ-anthracene-9-carboxylato)bis[(anthracene-9-carboxylato)(2,2′-bipyridyl)lanthanum(iii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914908/ https://www.ncbi.nlm.nih.gov/pubmed/21200503 http://dx.doi.org/10.1107/S1600536807062241 |
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