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Tetra­kis(μ-anthracene-9-carboxyl­ato)bis­[(anthracene-9-carboxyl­ato)(2,2′-bipyrid­yl)lanthanum(III)]

The title complex, [La(2)(C(15)H(9)O(2))(6)(C(10)H(8)N(2))(2)], has a centrosymmetric binuclear cage structure in which two La(III )atoms are both nine-coordinated and bridged by four anthracene-9-carboxyl­ate ligands, with an La⋯La separation of 4.0880 (4) Å. The remaining coordination sites are oc...

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Detalles Bibliográficos
Autores principales: Liu, Chun-Sen, Yan, Li-Fen, Chang, Ze, Wang, Jun-Jie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914908/
https://www.ncbi.nlm.nih.gov/pubmed/21200503
http://dx.doi.org/10.1107/S1600536807062241
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author Liu, Chun-Sen
Yan, Li-Fen
Chang, Ze
Wang, Jun-Jie
author_facet Liu, Chun-Sen
Yan, Li-Fen
Chang, Ze
Wang, Jun-Jie
author_sort Liu, Chun-Sen
collection PubMed
description The title complex, [La(2)(C(15)H(9)O(2))(6)(C(10)H(8)N(2))(2)], has a centrosymmetric binuclear cage structure in which two La(III )atoms are both nine-coordinated and bridged by four anthracene-9-carboxyl­ate ligands, with an La⋯La separation of 4.0880 (4) Å. The remaining coordination sites are occupied by two N atoms of a 2,2′-bipyridine (bipy) and two O atoms of an anthracene-9-carboxyl­ate ligand. The six anthracene-9-carboxyl­ate groups coordinate each La(III )atom in three different ways. Adjacent discrete dinuclear units are arranged into a one-dimensional chain along the [111] direction by inter­molecular π–π stacking inter­actions, with a centroid–centroid separation of 3.704 (7) Å.
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spelling pubmed-29149082010-12-30 Tetra­kis(μ-anthracene-9-carboxyl­ato)bis­[(anthracene-9-carboxyl­ato)(2,2′-bipyrid­yl)lanthanum(III)] Liu, Chun-Sen Yan, Li-Fen Chang, Ze Wang, Jun-Jie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [La(2)(C(15)H(9)O(2))(6)(C(10)H(8)N(2))(2)], has a centrosymmetric binuclear cage structure in which two La(III )atoms are both nine-coordinated and bridged by four anthracene-9-carboxyl­ate ligands, with an La⋯La separation of 4.0880 (4) Å. The remaining coordination sites are occupied by two N atoms of a 2,2′-bipyridine (bipy) and two O atoms of an anthracene-9-carboxyl­ate ligand. The six anthracene-9-carboxyl­ate groups coordinate each La(III )atom in three different ways. Adjacent discrete dinuclear units are arranged into a one-dimensional chain along the [111] direction by inter­molecular π–π stacking inter­actions, with a centroid–centroid separation of 3.704 (7) Å. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914908/ /pubmed/21200503 http://dx.doi.org/10.1107/S1600536807062241 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Liu, Chun-Sen
Yan, Li-Fen
Chang, Ze
Wang, Jun-Jie
Tetra­kis(μ-anthracene-9-carboxyl­ato)bis­[(anthracene-9-carboxyl­ato)(2,2′-bipyrid­yl)lanthanum(III)]
title Tetra­kis(μ-anthracene-9-carboxyl­ato)bis­[(anthracene-9-carboxyl­ato)(2,2′-bipyrid­yl)lanthanum(III)]
title_full Tetra­kis(μ-anthracene-9-carboxyl­ato)bis­[(anthracene-9-carboxyl­ato)(2,2′-bipyrid­yl)lanthanum(III)]
title_fullStr Tetra­kis(μ-anthracene-9-carboxyl­ato)bis­[(anthracene-9-carboxyl­ato)(2,2′-bipyrid­yl)lanthanum(III)]
title_full_unstemmed Tetra­kis(μ-anthracene-9-carboxyl­ato)bis­[(anthracene-9-carboxyl­ato)(2,2′-bipyrid­yl)lanthanum(III)]
title_short Tetra­kis(μ-anthracene-9-carboxyl­ato)bis­[(anthracene-9-carboxyl­ato)(2,2′-bipyrid­yl)lanthanum(III)]
title_sort tetra­kis(μ-anthracene-9-carboxyl­ato)bis­[(anthracene-9-carboxyl­ato)(2,2′-bipyrid­yl)lanthanum(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914908/
https://www.ncbi.nlm.nih.gov/pubmed/21200503
http://dx.doi.org/10.1107/S1600536807062241
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AT changze tetrakismanthracene9carboxylatobisanthracene9carboxylato22bipyridyllanthanumiii
AT wangjunjie tetrakismanthracene9carboxylatobisanthracene9carboxylato22bipyridyllanthanumiii