μ-Acetato-κ(2) O:O′-[7,23-dibenzyl-15,31-dichloro-3,7,11,19,23,27-hexa­azatri­cyclo­[27.3.1.1(13,17)]tetra­triconta-1(32),2,11,13,15,17(34),18,27,29(33),30-deca­ene-33,34-diolato-κ(10) N (4),N (5),N (6),O (1),O (2):N (1),N (2),N (3),O (1),O (2)]dinickel(II) per­chlorate acetonitrile disolvate

The title complex, [Ni(2)(C(42)H(46)Cl(2)N(6)O(2))(C(2)H(3)O(2))]ClO(4)·2CH(3)CN, was synthesized by condensation of 2,6-diformyl-4-chloro­phenol with N,N-bis­(amino­prop­yl)benzyl­amine in the presence of Ni(II) ions. The ligand is a 28-membered macrocycle with two identical pendant arms. The coord...

Descripción completa

Detalles Bibliográficos
Autores principales: Kong, Juan, Zhou, Hong, Pan, Zhi-Quan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914910/
https://www.ncbi.nlm.nih.gov/pubmed/21200528
http://dx.doi.org/10.1107/S1600536807061399
_version_ 1782184813915013120
author Kong, Juan
Zhou, Hong
Pan, Zhi-Quan
author_facet Kong, Juan
Zhou, Hong
Pan, Zhi-Quan
author_sort Kong, Juan
collection PubMed
description The title complex, [Ni(2)(C(42)H(46)Cl(2)N(6)O(2))(C(2)H(3)O(2))]ClO(4)·2CH(3)CN, was synthesized by condensation of 2,6-diformyl-4-chloro­phenol with N,N-bis­(amino­prop­yl)benzyl­amine in the presence of Ni(II) ions. The ligand is a 28-membered macrocycle with two identical pendant arms. The coordination geometries of the Ni atoms are both octa­hedral. The two Ni atoms are bridged by two phenolate O atoms of the macrocyclic ligand and one acetate ligand, with an Ni⋯Ni distance of 3.147 (4) Å.
format Text
id pubmed-2914910
institution National Center for Biotechnology Information
language English
publishDate 2007
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29149102010-12-30 μ-Acetato-κ(2) O:O′-[7,23-dibenzyl-15,31-dichloro-3,7,11,19,23,27-hexa­azatri­cyclo­[27.3.1.1(13,17)]tetra­triconta-1(32),2,11,13,15,17(34),18,27,29(33),30-deca­ene-33,34-diolato-κ(10) N (4),N (5),N (6),O (1),O (2):N (1),N (2),N (3),O (1),O (2)]dinickel(II) per­chlorate acetonitrile disolvate Kong, Juan Zhou, Hong Pan, Zhi-Quan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ni(2)(C(42)H(46)Cl(2)N(6)O(2))(C(2)H(3)O(2))]ClO(4)·2CH(3)CN, was synthesized by condensation of 2,6-diformyl-4-chloro­phenol with N,N-bis­(amino­prop­yl)benzyl­amine in the presence of Ni(II) ions. The ligand is a 28-membered macrocycle with two identical pendant arms. The coordination geometries of the Ni atoms are both octa­hedral. The two Ni atoms are bridged by two phenolate O atoms of the macrocyclic ligand and one acetate ligand, with an Ni⋯Ni distance of 3.147 (4) Å. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914910/ /pubmed/21200528 http://dx.doi.org/10.1107/S1600536807061399 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Kong, Juan
Zhou, Hong
Pan, Zhi-Quan
μ-Acetato-κ(2) O:O′-[7,23-dibenzyl-15,31-dichloro-3,7,11,19,23,27-hexa­azatri­cyclo­[27.3.1.1(13,17)]tetra­triconta-1(32),2,11,13,15,17(34),18,27,29(33),30-deca­ene-33,34-diolato-κ(10) N (4),N (5),N (6),O (1),O (2):N (1),N (2),N (3),O (1),O (2)]dinickel(II) per­chlorate acetonitrile disolvate
title μ-Acetato-κ(2) O:O′-[7,23-dibenzyl-15,31-dichloro-3,7,11,19,23,27-hexa­azatri­cyclo­[27.3.1.1(13,17)]tetra­triconta-1(32),2,11,13,15,17(34),18,27,29(33),30-deca­ene-33,34-diolato-κ(10) N (4),N (5),N (6),O (1),O (2):N (1),N (2),N (3),O (1),O (2)]dinickel(II) per­chlorate acetonitrile disolvate
title_full μ-Acetato-κ(2) O:O′-[7,23-dibenzyl-15,31-dichloro-3,7,11,19,23,27-hexa­azatri­cyclo­[27.3.1.1(13,17)]tetra­triconta-1(32),2,11,13,15,17(34),18,27,29(33),30-deca­ene-33,34-diolato-κ(10) N (4),N (5),N (6),O (1),O (2):N (1),N (2),N (3),O (1),O (2)]dinickel(II) per­chlorate acetonitrile disolvate
title_fullStr μ-Acetato-κ(2) O:O′-[7,23-dibenzyl-15,31-dichloro-3,7,11,19,23,27-hexa­azatri­cyclo­[27.3.1.1(13,17)]tetra­triconta-1(32),2,11,13,15,17(34),18,27,29(33),30-deca­ene-33,34-diolato-κ(10) N (4),N (5),N (6),O (1),O (2):N (1),N (2),N (3),O (1),O (2)]dinickel(II) per­chlorate acetonitrile disolvate
title_full_unstemmed μ-Acetato-κ(2) O:O′-[7,23-dibenzyl-15,31-dichloro-3,7,11,19,23,27-hexa­azatri­cyclo­[27.3.1.1(13,17)]tetra­triconta-1(32),2,11,13,15,17(34),18,27,29(33),30-deca­ene-33,34-diolato-κ(10) N (4),N (5),N (6),O (1),O (2):N (1),N (2),N (3),O (1),O (2)]dinickel(II) per­chlorate acetonitrile disolvate
title_short μ-Acetato-κ(2) O:O′-[7,23-dibenzyl-15,31-dichloro-3,7,11,19,23,27-hexa­azatri­cyclo­[27.3.1.1(13,17)]tetra­triconta-1(32),2,11,13,15,17(34),18,27,29(33),30-deca­ene-33,34-diolato-κ(10) N (4),N (5),N (6),O (1),O (2):N (1),N (2),N (3),O (1),O (2)]dinickel(II) per­chlorate acetonitrile disolvate
title_sort μ-acetato-κ(2) o:o′-[7,23-dibenzyl-15,31-dichloro-3,7,11,19,23,27-hexa­azatri­cyclo­[27.3.1.1(13,17)]tetra­triconta-1(32),2,11,13,15,17(34),18,27,29(33),30-deca­ene-33,34-diolato-κ(10) n (4),n (5),n (6),o (1),o (2):n (1),n (2),n (3),o (1),o (2)]dinickel(ii) per­chlorate acetonitrile disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914910/
https://www.ncbi.nlm.nih.gov/pubmed/21200528
http://dx.doi.org/10.1107/S1600536807061399
work_keys_str_mv AT kongjuan macetatok2oo723dibenzyl1531dichloro3711192327hexaazatricyclo273111317tetratriconta132211131517341827293330decaene3334diolatok10n4n5n6o1o2n1n2n3o1o2dinickeliiperchlorateacetonitriledisolvate
AT zhouhong macetatok2oo723dibenzyl1531dichloro3711192327hexaazatricyclo273111317tetratriconta132211131517341827293330decaene3334diolatok10n4n5n6o1o2n1n2n3o1o2dinickeliiperchlorateacetonitriledisolvate
AT panzhiquan macetatok2oo723dibenzyl1531dichloro3711192327hexaazatricyclo273111317tetratriconta132211131517341827293330decaene3334diolatok10n4n5n6o1o2n1n2n3o1o2dinickeliiperchlorateacetonitriledisolvate

Ejemplares similares