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(Salicylato)[tris­(1-methyl-1H-benz­imidazol-2-ylmeth­yl)amine]copper(II) perchlorate dimethyl­formamide disolvate

In the title complex, [Cu(C(7)H(5)O(3))(C(27)H(27)N(7))]ClO(4)·2C(3)H(7)NO, the Cu(II) ion is five-coordinated by four N atoms from the tris­(1-methyl-1H-benzimidazol-2-ylmeth­yl)amine ligand and an O atom of the monodentate salicylate ligand. The N(4)O donor set defines a coordination geometry inte...

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Detalles Bibliográficos
Autores principales: Wu, Huilu, Yun, Ruirui, Ding, Jian, Yuan, Jingkun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914911/
https://www.ncbi.nlm.nih.gov/pubmed/21200537
http://dx.doi.org/10.1107/S1600536807061661
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author Wu, Huilu
Yun, Ruirui
Ding, Jian
Yuan, Jingkun
author_facet Wu, Huilu
Yun, Ruirui
Ding, Jian
Yuan, Jingkun
author_sort Wu, Huilu
collection PubMed
description In the title complex, [Cu(C(7)H(5)O(3))(C(27)H(27)N(7))]ClO(4)·2C(3)H(7)NO, the Cu(II) ion is five-coordinated by four N atoms from the tris­(1-methyl-1H-benzimidazol-2-ylmeth­yl)amine ligand and an O atom of the monodentate salicylate ligand. The N(4)O donor set defines a coordination geometry inter­mediate between square-pyramidal and trigonal–bipyramidal. The crystal structure is stabilized by O—H⋯O inter­actions. The atoms of the aromatic ring of the salicylate ligand are disordered over two sites of equal occupancy. In addition, one of the dimethyl­formamide solvent mol­ecules is partially disordered over two positions, of approximately equal occupancy.
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spelling pubmed-29149112010-12-30 (Salicylato)[tris­(1-methyl-1H-benz­imidazol-2-ylmeth­yl)amine]copper(II) perchlorate dimethyl­formamide disolvate Wu, Huilu Yun, Ruirui Ding, Jian Yuan, Jingkun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(7)H(5)O(3))(C(27)H(27)N(7))]ClO(4)·2C(3)H(7)NO, the Cu(II) ion is five-coordinated by four N atoms from the tris­(1-methyl-1H-benzimidazol-2-ylmeth­yl)amine ligand and an O atom of the monodentate salicylate ligand. The N(4)O donor set defines a coordination geometry inter­mediate between square-pyramidal and trigonal–bipyramidal. The crystal structure is stabilized by O—H⋯O inter­actions. The atoms of the aromatic ring of the salicylate ligand are disordered over two sites of equal occupancy. In addition, one of the dimethyl­formamide solvent mol­ecules is partially disordered over two positions, of approximately equal occupancy. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914911/ /pubmed/21200537 http://dx.doi.org/10.1107/S1600536807061661 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Wu, Huilu
Yun, Ruirui
Ding, Jian
Yuan, Jingkun
(Salicylato)[tris­(1-methyl-1H-benz­imidazol-2-ylmeth­yl)amine]copper(II) perchlorate dimethyl­formamide disolvate
title (Salicylato)[tris­(1-methyl-1H-benz­imidazol-2-ylmeth­yl)amine]copper(II) perchlorate dimethyl­formamide disolvate
title_full (Salicylato)[tris­(1-methyl-1H-benz­imidazol-2-ylmeth­yl)amine]copper(II) perchlorate dimethyl­formamide disolvate
title_fullStr (Salicylato)[tris­(1-methyl-1H-benz­imidazol-2-ylmeth­yl)amine]copper(II) perchlorate dimethyl­formamide disolvate
title_full_unstemmed (Salicylato)[tris­(1-methyl-1H-benz­imidazol-2-ylmeth­yl)amine]copper(II) perchlorate dimethyl­formamide disolvate
title_short (Salicylato)[tris­(1-methyl-1H-benz­imidazol-2-ylmeth­yl)amine]copper(II) perchlorate dimethyl­formamide disolvate
title_sort (salicylato)[tris­(1-methyl-1h-benz­imidazol-2-ylmeth­yl)amine]copper(ii) perchlorate dimethyl­formamide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914911/
https://www.ncbi.nlm.nih.gov/pubmed/21200537
http://dx.doi.org/10.1107/S1600536807061661
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