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(Salicylato)[tris(1-methyl-1H-benzimidazol-2-ylmethyl)amine]copper(II) perchlorate dimethylformamide disolvate
In the title complex, [Cu(C(7)H(5)O(3))(C(27)H(27)N(7))]ClO(4)·2C(3)H(7)NO, the Cu(II) ion is five-coordinated by four N atoms from the tris(1-methyl-1H-benzimidazol-2-ylmethyl)amine ligand and an O atom of the monodentate salicylate ligand. The N(4)O donor set defines a coordination geometry inte...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914911/ https://www.ncbi.nlm.nih.gov/pubmed/21200537 http://dx.doi.org/10.1107/S1600536807061661 |
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author | Wu, Huilu Yun, Ruirui Ding, Jian Yuan, Jingkun |
author_facet | Wu, Huilu Yun, Ruirui Ding, Jian Yuan, Jingkun |
author_sort | Wu, Huilu |
collection | PubMed |
description | In the title complex, [Cu(C(7)H(5)O(3))(C(27)H(27)N(7))]ClO(4)·2C(3)H(7)NO, the Cu(II) ion is five-coordinated by four N atoms from the tris(1-methyl-1H-benzimidazol-2-ylmethyl)amine ligand and an O atom of the monodentate salicylate ligand. The N(4)O donor set defines a coordination geometry intermediate between square-pyramidal and trigonal–bipyramidal. The crystal structure is stabilized by O—H⋯O interactions. The atoms of the aromatic ring of the salicylate ligand are disordered over two sites of equal occupancy. In addition, one of the dimethylformamide solvent molecules is partially disordered over two positions, of approximately equal occupancy. |
format | Text |
id | pubmed-2914911 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29149112010-12-30 (Salicylato)[tris(1-methyl-1H-benzimidazol-2-ylmethyl)amine]copper(II) perchlorate dimethylformamide disolvate Wu, Huilu Yun, Ruirui Ding, Jian Yuan, Jingkun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(7)H(5)O(3))(C(27)H(27)N(7))]ClO(4)·2C(3)H(7)NO, the Cu(II) ion is five-coordinated by four N atoms from the tris(1-methyl-1H-benzimidazol-2-ylmethyl)amine ligand and an O atom of the monodentate salicylate ligand. The N(4)O donor set defines a coordination geometry intermediate between square-pyramidal and trigonal–bipyramidal. The crystal structure is stabilized by O—H⋯O interactions. The atoms of the aromatic ring of the salicylate ligand are disordered over two sites of equal occupancy. In addition, one of the dimethylformamide solvent molecules is partially disordered over two positions, of approximately equal occupancy. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914911/ /pubmed/21200537 http://dx.doi.org/10.1107/S1600536807061661 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Wu, Huilu Yun, Ruirui Ding, Jian Yuan, Jingkun (Salicylato)[tris(1-methyl-1H-benzimidazol-2-ylmethyl)amine]copper(II) perchlorate dimethylformamide disolvate |
title | (Salicylato)[tris(1-methyl-1H-benzimidazol-2-ylmethyl)amine]copper(II) perchlorate dimethylformamide disolvate |
title_full | (Salicylato)[tris(1-methyl-1H-benzimidazol-2-ylmethyl)amine]copper(II) perchlorate dimethylformamide disolvate |
title_fullStr | (Salicylato)[tris(1-methyl-1H-benzimidazol-2-ylmethyl)amine]copper(II) perchlorate dimethylformamide disolvate |
title_full_unstemmed | (Salicylato)[tris(1-methyl-1H-benzimidazol-2-ylmethyl)amine]copper(II) perchlorate dimethylformamide disolvate |
title_short | (Salicylato)[tris(1-methyl-1H-benzimidazol-2-ylmethyl)amine]copper(II) perchlorate dimethylformamide disolvate |
title_sort | (salicylato)[tris(1-methyl-1h-benzimidazol-2-ylmethyl)amine]copper(ii) perchlorate dimethylformamide disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914911/ https://www.ncbi.nlm.nih.gov/pubmed/21200537 http://dx.doi.org/10.1107/S1600536807061661 |
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