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Poly[[[(1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato)manganese(II)]-μ(3)-4,4′-oxydibenzoato] monohydrate]
In the title compound, {[Mn(C(16)H(18)N(3)O(3))(C(14)H(8)O(5))]·H(2)O}(n), the unique Mn(II) ion is coordinated by two O atoms from a chelating 1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylate ligand and three O atoms from three 4,4′-oxydibenzoate ligands, forming a dis...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2007
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914913/ https://www.ncbi.nlm.nih.gov/pubmed/21200557 http://dx.doi.org/10.1107/S1600536807060825 |
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author | Hong, Jun |
author_facet | Hong, Jun |
author_sort | Hong, Jun |
collection | PubMed |
description | In the title compound, {[Mn(C(16)H(18)N(3)O(3))(C(14)H(8)O(5))]·H(2)O}(n), the unique Mn(II) ion is coordinated by two O atoms from a chelating 1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylate ligand and three O atoms from three 4,4′-oxydibenzoate ligands, forming a distorted square-pyramidal coordination environment. In the crystal structure, centrosymmetric dinuclear manganese units are linked via 4,4′-oxydibenzoate ligands into one-dimensional chains; these chains are, in turn, connected via intermolecular N—H⋯O and O—H⋯O hydrogen bonds to form a two-dimensional supramolecular network. The O atom of the solvent water molecule is disordered over two sites with equal occupancies; the attached H atoms are common to both sites. |
format | Text |
id | pubmed-2914913 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29149132010-12-30 Poly[[[(1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato)manganese(II)]-μ(3)-4,4′-oxydibenzoato] monohydrate] Hong, Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Mn(C(16)H(18)N(3)O(3))(C(14)H(8)O(5))]·H(2)O}(n), the unique Mn(II) ion is coordinated by two O atoms from a chelating 1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylate ligand and three O atoms from three 4,4′-oxydibenzoate ligands, forming a distorted square-pyramidal coordination environment. In the crystal structure, centrosymmetric dinuclear manganese units are linked via 4,4′-oxydibenzoate ligands into one-dimensional chains; these chains are, in turn, connected via intermolecular N—H⋯O and O—H⋯O hydrogen bonds to form a two-dimensional supramolecular network. The O atom of the solvent water molecule is disordered over two sites with equal occupancies; the attached H atoms are common to both sites. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914913/ /pubmed/21200557 http://dx.doi.org/10.1107/S1600536807060825 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Hong, Jun Poly[[[(1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato)manganese(II)]-μ(3)-4,4′-oxydibenzoato] monohydrate] |
title | Poly[[[(1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato)manganese(II)]-μ(3)-4,4′-oxydibenzoato] monohydrate] |
title_full | Poly[[[(1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato)manganese(II)]-μ(3)-4,4′-oxydibenzoato] monohydrate] |
title_fullStr | Poly[[[(1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato)manganese(II)]-μ(3)-4,4′-oxydibenzoato] monohydrate] |
title_full_unstemmed | Poly[[[(1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato)manganese(II)]-μ(3)-4,4′-oxydibenzoato] monohydrate] |
title_short | Poly[[[(1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato)manganese(II)]-μ(3)-4,4′-oxydibenzoato] monohydrate] |
title_sort | poly[[[(1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylato)manganese(ii)]-μ(3)-4,4′-oxydibenzoato] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914913/ https://www.ncbi.nlm.nih.gov/pubmed/21200557 http://dx.doi.org/10.1107/S1600536807060825 |
work_keys_str_mv | AT hongjun poly1ethyl6fluoro4oxo7piperazin1yl14dihydroquinoline3carboxylatomanganeseiim344oxydibenzoatomonohydrate |