μ-Bromido-dibromido-μ-hydroxido-bis­[(4S)-2-halo-6-(4-isopropyl-4,5-dihydro­oxazol-2-yl)pyridine]dicopper(II) (halo: Cl/Br = 3:1)

The crystal structure of the title complex, [Cu(2)Br(3)(OH)(C(11)H(13)Br(0.5)Cl(1.5)N(2)O)(2)], consists of two (2-halo-6-oxazolin­yl)pyridine·CuBr units bridged by a Br atom and a hydroxide group. The Cu(II) atoms are five-coordinate with an (N,N)BrCu(Br)(OH) distorted tetra­gonal–pyramidal core, a...

Descripción completa

Detalles Bibliográficos
Autores principales: Laungani, Andy Ch., Keller, Manfred, Breit, Bernhard
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914915/
https://www.ncbi.nlm.nih.gov/pubmed/21200582
http://dx.doi.org/10.1107/S1600536807058862
Descripción
Sumario:The crystal structure of the title complex, [Cu(2)Br(3)(OH)(C(11)H(13)Br(0.5)Cl(1.5)N(2)O)(2)], consists of two (2-halo-6-oxazolin­yl)pyridine·CuBr units bridged by a Br atom and a hydroxide group. The Cu(II) atoms are five-coordinate with an (N,N)BrCu(Br)(OH) distorted tetra­gonal–pyramidal core, and relatively short contacts to the bridging atoms (Cu—μ-OH and Cu—μ-Br). There are two symmetry-independent half-mol­ecules in the asymmetric unit, which differ only in the arrangement of the isopropyl group. The mol­ecules are located on a twofold rotation axes.

Ejemplares similares