μ-Bromido-dibromido-μ-hydroxido-bis­[(4S)-2-halo-6-(4-isopropyl-4,5-dihydro­oxazol-2-yl)pyridine]dicopper(II) (halo: Cl/Br = 3:1)

The crystal structure of the title complex, [Cu(2)Br(3)(OH)(C(11)H(13)Br(0.5)Cl(1.5)N(2)O)(2)], consists of two (2-halo-6-oxazolin­yl)pyridine·CuBr units bridged by a Br atom and a hydroxide group. The Cu(II) atoms are five-coordinate with an (N,N)BrCu(Br)(OH) distorted tetra­gonal–pyramidal core, a...

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Detalles Bibliográficos
Autores principales: Laungani, Andy Ch., Keller, Manfred, Breit, Bernhard
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914915/
https://www.ncbi.nlm.nih.gov/pubmed/21200582
http://dx.doi.org/10.1107/S1600536807058862
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author Laungani, Andy Ch.
Keller, Manfred
Breit, Bernhard
author_facet Laungani, Andy Ch.
Keller, Manfred
Breit, Bernhard
author_sort Laungani, Andy Ch.
collection PubMed
description The crystal structure of the title complex, [Cu(2)Br(3)(OH)(C(11)H(13)Br(0.5)Cl(1.5)N(2)O)(2)], consists of two (2-halo-6-oxazolin­yl)pyridine·CuBr units bridged by a Br atom and a hydroxide group. The Cu(II) atoms are five-coordinate with an (N,N)BrCu(Br)(OH) distorted tetra­gonal–pyramidal core, and relatively short contacts to the bridging atoms (Cu—μ-OH and Cu—μ-Br). There are two symmetry-independent half-mol­ecules in the asymmetric unit, which differ only in the arrangement of the isopropyl group. The mol­ecules are located on a twofold rotation axes.
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spelling pubmed-29149152010-12-30 μ-Bromido-dibromido-μ-hydroxido-bis­[(4S)-2-halo-6-(4-isopropyl-4,5-dihydro­oxazol-2-yl)pyridine]dicopper(II) (halo: Cl/Br = 3:1) Laungani, Andy Ch. Keller, Manfred Breit, Bernhard Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title complex, [Cu(2)Br(3)(OH)(C(11)H(13)Br(0.5)Cl(1.5)N(2)O)(2)], consists of two (2-halo-6-oxazolin­yl)pyridine·CuBr units bridged by a Br atom and a hydroxide group. The Cu(II) atoms are five-coordinate with an (N,N)BrCu(Br)(OH) distorted tetra­gonal–pyramidal core, and relatively short contacts to the bridging atoms (Cu—μ-OH and Cu—μ-Br). There are two symmetry-independent half-mol­ecules in the asymmetric unit, which differ only in the arrangement of the isopropyl group. The mol­ecules are located on a twofold rotation axes. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914915/ /pubmed/21200582 http://dx.doi.org/10.1107/S1600536807058862 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Laungani, Andy Ch.
Keller, Manfred
Breit, Bernhard
μ-Bromido-dibromido-μ-hydroxido-bis­[(4S)-2-halo-6-(4-isopropyl-4,5-dihydro­oxazol-2-yl)pyridine]dicopper(II) (halo: Cl/Br = 3:1)
title μ-Bromido-dibromido-μ-hydroxido-bis­[(4S)-2-halo-6-(4-isopropyl-4,5-dihydro­oxazol-2-yl)pyridine]dicopper(II) (halo: Cl/Br = 3:1)
title_full μ-Bromido-dibromido-μ-hydroxido-bis­[(4S)-2-halo-6-(4-isopropyl-4,5-dihydro­oxazol-2-yl)pyridine]dicopper(II) (halo: Cl/Br = 3:1)
title_fullStr μ-Bromido-dibromido-μ-hydroxido-bis­[(4S)-2-halo-6-(4-isopropyl-4,5-dihydro­oxazol-2-yl)pyridine]dicopper(II) (halo: Cl/Br = 3:1)
title_full_unstemmed μ-Bromido-dibromido-μ-hydroxido-bis­[(4S)-2-halo-6-(4-isopropyl-4,5-dihydro­oxazol-2-yl)pyridine]dicopper(II) (halo: Cl/Br = 3:1)
title_short μ-Bromido-dibromido-μ-hydroxido-bis­[(4S)-2-halo-6-(4-isopropyl-4,5-dihydro­oxazol-2-yl)pyridine]dicopper(II) (halo: Cl/Br = 3:1)
title_sort μ-bromido-dibromido-μ-hydroxido-bis­[(4s)-2-halo-6-(4-isopropyl-4,5-dihydro­oxazol-2-yl)pyridine]dicopper(ii) (halo: cl/br = 3:1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914915/
https://www.ncbi.nlm.nih.gov/pubmed/21200582
http://dx.doi.org/10.1107/S1600536807058862
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AT kellermanfred mbromidodibromidomhydroxidobis4s2halo64isopropyl45dihydrooxazol2ylpyridinedicopperiihaloclbr31
AT breitbernhard mbromidodibromidomhydroxidobis4s2halo64isopropyl45dihydrooxazol2ylpyridinedicopperiihaloclbr31

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