(Isopropyl xanthato-κ(2) S,S′)bis­(1,10-phenanthroline-κ(2) N,N′)sodium(I)

The title compound, [Na(C(4)H(7)OS(2))(C(12)H(8)N(2))(2)], is monomeric, with the Na atom chelated by the S atoms of an i-propylxanthate ligand and the N atoms of two 1,10-phenanthroline (phen) ligands. The Na atom is six-coordinate in a distorted trigonal anti­prism. A number of π–π stacking inter­...

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Detalles Bibliográficos
Autor principal: Li, Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914917/
https://www.ncbi.nlm.nih.gov/pubmed/21200601
http://dx.doi.org/10.1107/S1600536807061910
Descripción
Sumario:The title compound, [Na(C(4)H(7)OS(2))(C(12)H(8)N(2))(2)], is monomeric, with the Na atom chelated by the S atoms of an i-propylxanthate ligand and the N atoms of two 1,10-phenanthroline (phen) ligands. The Na atom is six-coordinate in a distorted trigonal anti­prism. A number of π–π stacking inter­actions involving the phen rings help to consolidate the crystal packing (centroid–centroid distances lie in the range 3.338–3.443 Å).

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