(Isopropyl xanthato-κ(2) S,S′)bis­(1,10-phenanthroline-κ(2) N,N′)sodium(I)

The title compound, [Na(C(4)H(7)OS(2))(C(12)H(8)N(2))(2)], is monomeric, with the Na atom chelated by the S atoms of an i-propylxanthate ligand and the N atoms of two 1,10-phenanthroline (phen) ligands. The Na atom is six-coordinate in a distorted trigonal anti­prism. A number of π–π stacking inter­...

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Detalles Bibliográficos
Autor principal: Li, Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914917/
https://www.ncbi.nlm.nih.gov/pubmed/21200601
http://dx.doi.org/10.1107/S1600536807061910
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author Li, Feng
author_facet Li, Feng
author_sort Li, Feng
collection PubMed
description The title compound, [Na(C(4)H(7)OS(2))(C(12)H(8)N(2))(2)], is monomeric, with the Na atom chelated by the S atoms of an i-propylxanthate ligand and the N atoms of two 1,10-phenanthroline (phen) ligands. The Na atom is six-coordinate in a distorted trigonal anti­prism. A number of π–π stacking inter­actions involving the phen rings help to consolidate the crystal packing (centroid–centroid distances lie in the range 3.338–3.443 Å).
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spelling pubmed-29149172010-12-30 (Isopropyl xanthato-κ(2) S,S′)bis­(1,10-phenanthroline-κ(2) N,N′)sodium(I) Li, Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Na(C(4)H(7)OS(2))(C(12)H(8)N(2))(2)], is monomeric, with the Na atom chelated by the S atoms of an i-propylxanthate ligand and the N atoms of two 1,10-phenanthroline (phen) ligands. The Na atom is six-coordinate in a distorted trigonal anti­prism. A number of π–π stacking inter­actions involving the phen rings help to consolidate the crystal packing (centroid–centroid distances lie in the range 3.338–3.443 Å). International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914917/ /pubmed/21200601 http://dx.doi.org/10.1107/S1600536807061910 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Li, Feng
(Isopropyl xanthato-κ(2) S,S′)bis­(1,10-phenanthroline-κ(2) N,N′)sodium(I)
title (Isopropyl xanthato-κ(2) S,S′)bis­(1,10-phenanthroline-κ(2) N,N′)sodium(I)
title_full (Isopropyl xanthato-κ(2) S,S′)bis­(1,10-phenanthroline-κ(2) N,N′)sodium(I)
title_fullStr (Isopropyl xanthato-κ(2) S,S′)bis­(1,10-phenanthroline-κ(2) N,N′)sodium(I)
title_full_unstemmed (Isopropyl xanthato-κ(2) S,S′)bis­(1,10-phenanthroline-κ(2) N,N′)sodium(I)
title_short (Isopropyl xanthato-κ(2) S,S′)bis­(1,10-phenanthroline-κ(2) N,N′)sodium(I)
title_sort (isopropyl xanthato-κ(2) s,s′)bis­(1,10-phenanthroline-κ(2) n,n′)sodium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914917/
https://www.ncbi.nlm.nih.gov/pubmed/21200601
http://dx.doi.org/10.1107/S1600536807061910
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