catena-Poly[[diazido­manganese(II)]bis­[μ-1-(4-pyridylmeth­yl)-1H-benzimidazole]]

In the title polymeric compound, [Mn(N(3))(2)(C(13)H(11)N(3))(2)](n), each Mn(II) centre is six-coordinated in an octahedral geometry by six N atoms from four 1-(4-pyridylmeth­yl)-1H-benzimidazole (L) ligands and two azide anions (N(3) (−)). Each of the Mn(II) ions lies on an inversion centre. The L...

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Detalles Bibliográficos
Autores principales: Liu, Chun-Sen, Wang, Jun-Jie, Yan, Li-Fen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914919/
https://www.ncbi.nlm.nih.gov/pubmed/21200603
http://dx.doi.org/10.1107/S1600536807062435
Descripción
Sumario:In the title polymeric compound, [Mn(N(3))(2)(C(13)H(11)N(3))(2)](n), each Mn(II) centre is six-coordinated in an octahedral geometry by six N atoms from four 1-(4-pyridylmeth­yl)-1H-benzimidazole (L) ligands and two azide anions (N(3) (−)). Each of the Mn(II) ions lies on an inversion centre. The L ligands and N(3) (−) anions bridge adjacent Mn(II) centres, generating a polymeric chain running along the [110] direction. Adjacent polymeric chains are arranged in a two-dimensional network parallel to the (001) plane, linked by C—H⋯N hydrogen bonds.

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