catena-Poly[[diazido­manganese(II)]bis­[μ-1-(4-pyridylmeth­yl)-1H-benzimidazole]]

In the title polymeric compound, [Mn(N(3))(2)(C(13)H(11)N(3))(2)](n), each Mn(II) centre is six-coordinated in an octahedral geometry by six N atoms from four 1-(4-pyridylmeth­yl)-1H-benzimidazole (L) ligands and two azide anions (N(3) (−)). Each of the Mn(II) ions lies on an inversion centre. The L...

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Detalles Bibliográficos
Autores principales: Liu, Chun-Sen, Wang, Jun-Jie, Yan, Li-Fen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914919/
https://www.ncbi.nlm.nih.gov/pubmed/21200603
http://dx.doi.org/10.1107/S1600536807062435
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author Liu, Chun-Sen
Wang, Jun-Jie
Yan, Li-Fen
author_facet Liu, Chun-Sen
Wang, Jun-Jie
Yan, Li-Fen
author_sort Liu, Chun-Sen
collection PubMed
description In the title polymeric compound, [Mn(N(3))(2)(C(13)H(11)N(3))(2)](n), each Mn(II) centre is six-coordinated in an octahedral geometry by six N atoms from four 1-(4-pyridylmeth­yl)-1H-benzimidazole (L) ligands and two azide anions (N(3) (−)). Each of the Mn(II) ions lies on an inversion centre. The L ligands and N(3) (−) anions bridge adjacent Mn(II) centres, generating a polymeric chain running along the [110] direction. Adjacent polymeric chains are arranged in a two-dimensional network parallel to the (001) plane, linked by C—H⋯N hydrogen bonds.
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spelling pubmed-29149192010-12-30 catena-Poly[[diazido­manganese(II)]bis­[μ-1-(4-pyridylmeth­yl)-1H-benzimidazole]] Liu, Chun-Sen Wang, Jun-Jie Yan, Li-Fen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymeric compound, [Mn(N(3))(2)(C(13)H(11)N(3))(2)](n), each Mn(II) centre is six-coordinated in an octahedral geometry by six N atoms from four 1-(4-pyridylmeth­yl)-1H-benzimidazole (L) ligands and two azide anions (N(3) (−)). Each of the Mn(II) ions lies on an inversion centre. The L ligands and N(3) (−) anions bridge adjacent Mn(II) centres, generating a polymeric chain running along the [110] direction. Adjacent polymeric chains are arranged in a two-dimensional network parallel to the (001) plane, linked by C—H⋯N hydrogen bonds. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914919/ /pubmed/21200603 http://dx.doi.org/10.1107/S1600536807062435 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Liu, Chun-Sen
Wang, Jun-Jie
Yan, Li-Fen
catena-Poly[[diazido­manganese(II)]bis­[μ-1-(4-pyridylmeth­yl)-1H-benzimidazole]]
title catena-Poly[[diazido­manganese(II)]bis­[μ-1-(4-pyridylmeth­yl)-1H-benzimidazole]]
title_full catena-Poly[[diazido­manganese(II)]bis­[μ-1-(4-pyridylmeth­yl)-1H-benzimidazole]]
title_fullStr catena-Poly[[diazido­manganese(II)]bis­[μ-1-(4-pyridylmeth­yl)-1H-benzimidazole]]
title_full_unstemmed catena-Poly[[diazido­manganese(II)]bis­[μ-1-(4-pyridylmeth­yl)-1H-benzimidazole]]
title_short catena-Poly[[diazido­manganese(II)]bis­[μ-1-(4-pyridylmeth­yl)-1H-benzimidazole]]
title_sort catena-poly[[diazido­manganese(ii)]bis­[μ-1-(4-pyridylmeth­yl)-1h-benzimidazole]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914919/
https://www.ncbi.nlm.nih.gov/pubmed/21200603
http://dx.doi.org/10.1107/S1600536807062435
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