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Poly[[aqua(1-naphthylacetato)cadmium(II)]-μ(3)-pyridin-3-olato]
In the title complex, [Cd(C(5)H(4)NO)(C(12)H(9)O(2))(H(2)O)](n), each Cd(II) atom is coordinated by two carboxylate O atoms from one 1-naphthylacetate ligand, two hydroxyl O atoms from two pyridin-3-olate ligands, one N atom from another pyridin-3-olate ligand and one water molecule, and displays...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2007
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914920/ https://www.ncbi.nlm.nih.gov/pubmed/21200605 http://dx.doi.org/10.1107/S1600536807062332 |
| Sumario: | In the title complex, [Cd(C(5)H(4)NO)(C(12)H(9)O(2))(H(2)O)](n), each Cd(II) atom is coordinated by two carboxylate O atoms from one 1-naphthylacetate ligand, two hydroxyl O atoms from two pyridin-3-olate ligands, one N atom from another pyridin-3-olate ligand and one water molecule, and displays a distorted octahedral coordination geometry. The compound forms infinite chains of pyridin-3-olate ligands bridging 1-naphthylacetate–Cd(II) units parallel to the b axis, with a Cd⋯Cd separation of 3.578 (2) Å. The chains are further self-assembled into a supramolecular network through intermolecular O—H⋯O hydrogen-bonding interactions. |
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