(Azido-κN)[6-meth­oxy-2-(2-pyridylmethyl­imino­meth­yl)phenolato-κ(3) N,N′,O (1)]copper(II)

The title compound, [Cu(C(14)H(13)N(2)O(2))(N(3))], is a monomeric neutral complex with one unsymmetrical 6-meth­oxy-2-(2-pyridylmethyl­imino­meth­yl)phenolate Schiff base ligand and one azide ligand. The mol­ecules are connected by a combination of two π–π inter­actions [centroid–centroid distances...

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Detalles Bibliográficos
Autor principal: Sun, Xuan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914922/
https://www.ncbi.nlm.nih.gov/pubmed/21200607
http://dx.doi.org/10.1107/S1600536807046260
Descripción
Sumario:The title compound, [Cu(C(14)H(13)N(2)O(2))(N(3))], is a monomeric neutral complex with one unsymmetrical 6-meth­oxy-2-(2-pyridylmethyl­imino­meth­yl)phenolate Schiff base ligand and one azide ligand. The mol­ecules are connected by a combination of two π–π inter­actions [centroid–centroid distances 3.359 (3) and 3.378 (2) Å] and one C—H⋯N hydrogen bond into a two-dimensional supra­molecular network structure.

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