Decaaqua­dioxidobis[μ(3)-N-(phospho­n­atometh­yl)imino­diacetato]­dizinc(II)­divanadium(IV) dihydrate

The title compound, [Zn(2)V(2)(C(5)H(6)NO(7)P)(2)O(2)(H(2)O)(10)]·2H(2)O, contains a [V(2)O(2)(pmida)(2)](4−) dimeric anionic unit [where H(4)pmida is N-(phosphono­meth­yl)imino­diacetic acid] lying on a centre of symmetry which is exo-coordinated via the two deprotonated phospho­nate groups to two Zn(2+) cations, with the coordination environment of Zn completed by five water mol­ecules. The crystal packing is mediated by an extensive network of strong and highly directional O—H⋯O hydrogen bonds involving the water mol­ecules (coordinated and uncoordinated) and the functional groups of pmida(4−), leading to a three-dimensional supra­molecular network.