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Decaaquadioxidobis[μ(3)-N-(phosphonatomethyl)iminodiacetato]dizinc(II)divanadium(IV) dihydrate
The title compound, [Zn(2)V(2)(C(5)H(6)NO(7)P)(2)O(2)(H(2)O)(10)]·2H(2)O, contains a [V(2)O(2)(pmida)(2)](4−) dimeric anionic unit [where H(4)pmida is N-(phosphonomethyl)iminodiacetic acid] lying on a centre of symmetry which is exo-coordinated via the two deprotonated phosphonate groups to two...
| Autores principales: | , , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2007
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914926/ https://www.ncbi.nlm.nih.gov/pubmed/21200612 http://dx.doi.org/10.1107/S1600536807062253 |
| _version_ | 1782184817798938624 |
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| author | Cunha-Silva, Luís Shi, Fa-Nian Klinowski, Jacek Trindade, Tito Rocha, João Almeida Paz, Filipe A. |
| author_facet | Cunha-Silva, Luís Shi, Fa-Nian Klinowski, Jacek Trindade, Tito Rocha, João Almeida Paz, Filipe A. |
| author_sort | Cunha-Silva, Luís |
| collection | PubMed |
| description | The title compound, [Zn(2)V(2)(C(5)H(6)NO(7)P)(2)O(2)(H(2)O)(10)]·2H(2)O, contains a [V(2)O(2)(pmida)(2)](4−) dimeric anionic unit [where H(4)pmida is N-(phosphonomethyl)iminodiacetic acid] lying on a centre of symmetry which is exo-coordinated via the two deprotonated phosphonate groups to two Zn(2+) cations, with the coordination environment of Zn completed by five water molecules. The crystal packing is mediated by an extensive network of strong and highly directional O—H⋯O hydrogen bonds involving the water molecules (coordinated and uncoordinated) and the functional groups of pmida(4−), leading to a three-dimensional supramolecular network. |
| format | Text |
| id | pubmed-2914926 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29149262010-12-30 Decaaquadioxidobis[μ(3)-N-(phosphonatomethyl)iminodiacetato]dizinc(II)divanadium(IV) dihydrate Cunha-Silva, Luís Shi, Fa-Nian Klinowski, Jacek Trindade, Tito Rocha, João Almeida Paz, Filipe A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(2)V(2)(C(5)H(6)NO(7)P)(2)O(2)(H(2)O)(10)]·2H(2)O, contains a [V(2)O(2)(pmida)(2)](4−) dimeric anionic unit [where H(4)pmida is N-(phosphonomethyl)iminodiacetic acid] lying on a centre of symmetry which is exo-coordinated via the two deprotonated phosphonate groups to two Zn(2+) cations, with the coordination environment of Zn completed by five water molecules. The crystal packing is mediated by an extensive network of strong and highly directional O—H⋯O hydrogen bonds involving the water molecules (coordinated and uncoordinated) and the functional groups of pmida(4−), leading to a three-dimensional supramolecular network. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914926/ /pubmed/21200612 http://dx.doi.org/10.1107/S1600536807062253 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
| spellingShingle | Metal-Organic Papers Cunha-Silva, Luís Shi, Fa-Nian Klinowski, Jacek Trindade, Tito Rocha, João Almeida Paz, Filipe A. Decaaquadioxidobis[μ(3)-N-(phosphonatomethyl)iminodiacetato]dizinc(II)divanadium(IV) dihydrate |
| title | Decaaquadioxidobis[μ(3)-N-(phosphonatomethyl)iminodiacetato]dizinc(II)divanadium(IV) dihydrate |
| title_full | Decaaquadioxidobis[μ(3)-N-(phosphonatomethyl)iminodiacetato]dizinc(II)divanadium(IV) dihydrate |
| title_fullStr | Decaaquadioxidobis[μ(3)-N-(phosphonatomethyl)iminodiacetato]dizinc(II)divanadium(IV) dihydrate |
| title_full_unstemmed | Decaaquadioxidobis[μ(3)-N-(phosphonatomethyl)iminodiacetato]dizinc(II)divanadium(IV) dihydrate |
| title_short | Decaaquadioxidobis[μ(3)-N-(phosphonatomethyl)iminodiacetato]dizinc(II)divanadium(IV) dihydrate |
| title_sort | decaaquadioxidobis[μ(3)-n-(phosphonatomethyl)iminodiacetato]dizinc(ii)divanadium(iv) dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914926/ https://www.ncbi.nlm.nih.gov/pubmed/21200612 http://dx.doi.org/10.1107/S1600536807062253 |
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