Bis[2-(pyrimidin-2-ylamino)pyrimidin­ium] hexa­molybdate

The title compound, (C(8)H(8)N(5))(2)[Mo(6)O(19)], was prepared by reaction of Mo(CO)(6) and dipyrimidylamine in refluxing toluene. The hexa­nuclear polyoxomolybdate anions lie on centres of inversion. Each 2-(pyrimidin-2-ylamino)pyrimidinium cation forms an intra­molecular N—H⋯N hydrogen bond and t...

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Detalles Bibliográficos
Autores principales: Yeh, Chun-Wei, Lin, Chia-Her, Chen, Jhy-Der
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914927/
https://www.ncbi.nlm.nih.gov/pubmed/21200613
http://dx.doi.org/10.1107/S1600536807062897
Descripción
Sumario:The title compound, (C(8)H(8)N(5))(2)[Mo(6)O(19)], was prepared by reaction of Mo(CO)(6) and dipyrimidylamine in refluxing toluene. The hexa­nuclear polyoxomolybdate anions lie on centres of inversion. Each 2-(pyrimidin-2-ylamino)pyrimidinium cation forms an intra­molecular N—H⋯N hydrogen bond and the cations are linked through self-complementary pairs of N—H⋯N hydrogen bonds into dimers across centres of inversion. The cations and anions are inter­linked through C—H⋯O contacts.

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