Bis[2-(pyrimidin-2-ylamino)pyrimidin­ium] hexa­molybdate

The title compound, (C(8)H(8)N(5))(2)[Mo(6)O(19)], was prepared by reaction of Mo(CO)(6) and dipyrimidylamine in refluxing toluene. The hexa­nuclear polyoxomolybdate anions lie on centres of inversion. Each 2-(pyrimidin-2-ylamino)pyrimidinium cation forms an intra­molecular N—H⋯N hydrogen bond and t...

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Detalles Bibliográficos
Autores principales: Yeh, Chun-Wei, Lin, Chia-Her, Chen, Jhy-Der
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914927/
https://www.ncbi.nlm.nih.gov/pubmed/21200613
http://dx.doi.org/10.1107/S1600536807062897
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author Yeh, Chun-Wei
Lin, Chia-Her
Chen, Jhy-Der
author_facet Yeh, Chun-Wei
Lin, Chia-Her
Chen, Jhy-Der
author_sort Yeh, Chun-Wei
collection PubMed
description The title compound, (C(8)H(8)N(5))(2)[Mo(6)O(19)], was prepared by reaction of Mo(CO)(6) and dipyrimidylamine in refluxing toluene. The hexa­nuclear polyoxomolybdate anions lie on centres of inversion. Each 2-(pyrimidin-2-ylamino)pyrimidinium cation forms an intra­molecular N—H⋯N hydrogen bond and the cations are linked through self-complementary pairs of N—H⋯N hydrogen bonds into dimers across centres of inversion. The cations and anions are inter­linked through C—H⋯O contacts.
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spelling pubmed-29149272010-12-30 Bis[2-(pyrimidin-2-ylamino)pyrimidin­ium] hexa­molybdate Yeh, Chun-Wei Lin, Chia-Her Chen, Jhy-Der Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(8)H(8)N(5))(2)[Mo(6)O(19)], was prepared by reaction of Mo(CO)(6) and dipyrimidylamine in refluxing toluene. The hexa­nuclear polyoxomolybdate anions lie on centres of inversion. Each 2-(pyrimidin-2-ylamino)pyrimidinium cation forms an intra­molecular N—H⋯N hydrogen bond and the cations are linked through self-complementary pairs of N—H⋯N hydrogen bonds into dimers across centres of inversion. The cations and anions are inter­linked through C—H⋯O contacts. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914927/ /pubmed/21200613 http://dx.doi.org/10.1107/S1600536807062897 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Yeh, Chun-Wei
Lin, Chia-Her
Chen, Jhy-Der
Bis[2-(pyrimidin-2-ylamino)pyrimidin­ium] hexa­molybdate
title Bis[2-(pyrimidin-2-ylamino)pyrimidin­ium] hexa­molybdate
title_full Bis[2-(pyrimidin-2-ylamino)pyrimidin­ium] hexa­molybdate
title_fullStr Bis[2-(pyrimidin-2-ylamino)pyrimidin­ium] hexa­molybdate
title_full_unstemmed Bis[2-(pyrimidin-2-ylamino)pyrimidin­ium] hexa­molybdate
title_short Bis[2-(pyrimidin-2-ylamino)pyrimidin­ium] hexa­molybdate
title_sort bis[2-(pyrimidin-2-ylamino)pyrimidin­ium] hexa­molybdate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914927/
https://www.ncbi.nlm.nih.gov/pubmed/21200613
http://dx.doi.org/10.1107/S1600536807062897
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AT linchiaher bis2pyrimidin2ylaminopyrimidiniumhexamolybdate
AT chenjhyder bis2pyrimidin2ylaminopyrimidiniumhexamolybdate

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