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Redetermination of tetra­kis(trimethyl­stann­yl)germane

Redetermination of the structure of the title compound, [Ge(SnMe(3))(4)] or [GeSn(4)(CH(3))(12)], previously refined from powder diffraction data only [Dinnebier, Bernatowicz, Helluy, Sebald, Wunschel, Fitch & van Smaalen et al. (2002 ▶). Acta Cryst. B58, 52–61], confirms that four bulky trimeth...

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Detalles Bibliográficos
Autores principales: Bauer, Matthew, Groy, Thomas L., Kouvetakis, John
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914933/
https://www.ncbi.nlm.nih.gov/pubmed/21200620
http://dx.doi.org/10.1107/S1600536807054724
Descripción
Sumario:Redetermination of the structure of the title compound, [Ge(SnMe(3))(4)] or [GeSn(4)(CH(3))(12)], previously refined from powder diffraction data only [Dinnebier, Bernatowicz, Helluy, Sebald, Wunschel, Fitch & van Smaalen et al. (2002 ▶). Acta Cryst. B58, 52–61], confirms that four bulky trimethyl­stannyl ligands surround the central Ge atom (site symmetry 1) in a tetra­hedral coordination.