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Bis[N (3)-(2-hydroxybenzoyl)pyridine-2-carboxamidrazonato-κ(3) N (1),N (2),O]manganese(II)
In the title compound, [Mn(C(13)H(11)N(4)O(2))(2)], the Mn atom is coordinated in a distorted octahedral manner by pyridyl N atoms, amidrazonato N atoms and carbamoy O atoms from two tridentate N (3)-salicyloylpyridine-2-carboxamidrazonato ligands. N—H⋯O hydrogen bonds result in the formation of tw...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914934/ https://www.ncbi.nlm.nih.gov/pubmed/21200622 http://dx.doi.org/10.1107/S1600536807063301 |
Sumario: | In the title compound, [Mn(C(13)H(11)N(4)O(2))(2)], the Mn atom is coordinated in a distorted octahedral manner by pyridyl N atoms, amidrazonato N atoms and carbamoy O atoms from two tridentate N (3)-salicyloylpyridine-2-carboxamidrazonato ligands. N—H⋯O hydrogen bonds result in the formation of two chains, one parallel to the b axis and the other one parallel to the c axis. These two chains are cross-linked, building up layers parallel to the (100) plane. |
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