Bis[N (3)-(2-hydroxy­benzo­yl)pyridine-2-carboxamidrazonato-κ(3) N (1),N (2),O]manganese(II)

In the title compound, [Mn(C(13)H(11)N(4)O(2))(2)], the Mn atom is coordinated in a distorted octa­hedral manner by pyridyl N atoms, amidrazonato N atoms and carbamoy O atoms from two tridentate N (3)-salicyloylpyridine-2-carboxamidrazonato ligands. N—H⋯O hydrogen bonds result in the formation of tw...

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Detalles Bibliográficos
Autor principal: Li, Yong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914934/
https://www.ncbi.nlm.nih.gov/pubmed/21200622
http://dx.doi.org/10.1107/S1600536807063301
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author Li, Yong
author_facet Li, Yong
author_sort Li, Yong
collection PubMed
description In the title compound, [Mn(C(13)H(11)N(4)O(2))(2)], the Mn atom is coordinated in a distorted octa­hedral manner by pyridyl N atoms, amidrazonato N atoms and carbamoy O atoms from two tridentate N (3)-salicyloylpyridine-2-carboxamidrazonato ligands. N—H⋯O hydrogen bonds result in the formation of two chains, one parallel to the b axis and the other one parallel to the c axis. These two chains are cross-linked, building up layers parallel to the (100) plane.
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spelling pubmed-29149342010-12-30 Bis[N (3)-(2-hydroxy­benzo­yl)pyridine-2-carboxamidrazonato-κ(3) N (1),N (2),O]manganese(II) Li, Yong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(13)H(11)N(4)O(2))(2)], the Mn atom is coordinated in a distorted octa­hedral manner by pyridyl N atoms, amidrazonato N atoms and carbamoy O atoms from two tridentate N (3)-salicyloylpyridine-2-carboxamidrazonato ligands. N—H⋯O hydrogen bonds result in the formation of two chains, one parallel to the b axis and the other one parallel to the c axis. These two chains are cross-linked, building up layers parallel to the (100) plane. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914934/ /pubmed/21200622 http://dx.doi.org/10.1107/S1600536807063301 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Li, Yong
Bis[N (3)-(2-hydroxy­benzo­yl)pyridine-2-carboxamidrazonato-κ(3) N (1),N (2),O]manganese(II)
title Bis[N (3)-(2-hydroxy­benzo­yl)pyridine-2-carboxamidrazonato-κ(3) N (1),N (2),O]manganese(II)
title_full Bis[N (3)-(2-hydroxy­benzo­yl)pyridine-2-carboxamidrazonato-κ(3) N (1),N (2),O]manganese(II)
title_fullStr Bis[N (3)-(2-hydroxy­benzo­yl)pyridine-2-carboxamidrazonato-κ(3) N (1),N (2),O]manganese(II)
title_full_unstemmed Bis[N (3)-(2-hydroxy­benzo­yl)pyridine-2-carboxamidrazonato-κ(3) N (1),N (2),O]manganese(II)
title_short Bis[N (3)-(2-hydroxy­benzo­yl)pyridine-2-carboxamidrazonato-κ(3) N (1),N (2),O]manganese(II)
title_sort bis[n (3)-(2-hydroxy­benzo­yl)pyridine-2-carboxamidrazonato-κ(3) n (1),n (2),o]manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914934/
https://www.ncbi.nlm.nih.gov/pubmed/21200622
http://dx.doi.org/10.1107/S1600536807063301
work_keys_str_mv AT liyong bisn32hydroxybenzoylpyridine2carboxamidrazonatok3n1n2omanganeseii

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