Bis(2,4-dibromo-6-formyl­phenolato-κ(2) O,O′)copper(II)

In the title compound, [Cu(C(7)H(3)Br(2)O(2))(2)], the Cu(II) atom, which lies on an inversion centre, is coordinated by four O atoms from two chelating bidentate 2,4-dibromo-6-formyl­phenolate ligands in a slightly distorted square-planar coordination geometry. In the crystal structure, short inter...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Guang Zhao, Zhang, Shu Hua, Liu, Zheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914936/
https://www.ncbi.nlm.nih.gov/pubmed/21200624
http://dx.doi.org/10.1107/S1600536807062769
_version_ 1782184820335443968
author Li, Guang Zhao
Zhang, Shu Hua
Liu, Zheng
author_facet Li, Guang Zhao
Zhang, Shu Hua
Liu, Zheng
author_sort Li, Guang Zhao
collection PubMed
description In the title compound, [Cu(C(7)H(3)Br(2)O(2))(2)], the Cu(II) atom, which lies on an inversion centre, is coordinated by four O atoms from two chelating bidentate 2,4-dibromo-6-formyl­phenolate ligands in a slightly distorted square-planar coordination geometry. In the crystal structure, short inter­molecular Br⋯Br [3.516 (4) and 3.653 (4) Å] and Cu⋯Br [3.255 (1) Å] contacts together with C—H⋯O hydrogen bonds generate a three-dimensional network.
format Text
id pubmed-2914936
institution National Center for Biotechnology Information
language English
publishDate 2007
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29149362010-12-30 Bis(2,4-dibromo-6-formyl­phenolato-κ(2) O,O′)copper(II) Li, Guang Zhao Zhang, Shu Hua Liu, Zheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(7)H(3)Br(2)O(2))(2)], the Cu(II) atom, which lies on an inversion centre, is coordinated by four O atoms from two chelating bidentate 2,4-dibromo-6-formyl­phenolate ligands in a slightly distorted square-planar coordination geometry. In the crystal structure, short inter­molecular Br⋯Br [3.516 (4) and 3.653 (4) Å] and Cu⋯Br [3.255 (1) Å] contacts together with C—H⋯O hydrogen bonds generate a three-dimensional network. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914936/ /pubmed/21200624 http://dx.doi.org/10.1107/S1600536807062769 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Li, Guang Zhao
Zhang, Shu Hua
Liu, Zheng
Bis(2,4-dibromo-6-formyl­phenolato-κ(2) O,O′)copper(II)
title Bis(2,4-dibromo-6-formyl­phenolato-κ(2) O,O′)copper(II)
title_full Bis(2,4-dibromo-6-formyl­phenolato-κ(2) O,O′)copper(II)
title_fullStr Bis(2,4-dibromo-6-formyl­phenolato-κ(2) O,O′)copper(II)
title_full_unstemmed Bis(2,4-dibromo-6-formyl­phenolato-κ(2) O,O′)copper(II)
title_short Bis(2,4-dibromo-6-formyl­phenolato-κ(2) O,O′)copper(II)
title_sort bis(2,4-dibromo-6-formyl­phenolato-κ(2) o,o′)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914936/
https://www.ncbi.nlm.nih.gov/pubmed/21200624
http://dx.doi.org/10.1107/S1600536807062769
work_keys_str_mv AT liguangzhao bis24dibromo6formylphenolatok2oocopperii
AT zhangshuhua bis24dibromo6formylphenolatok2oocopperii
AT liuzheng bis24dibromo6formylphenolatok2oocopperii

Ejemplares similares