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1H-Benzotriazol-3-ium (1H-benzotriazole-κN (3))trichloridocobaltate(II) monohydrate: a reformulation
The asymmetric unit of the title compound, (C(6)H(6)N(3))[CoCl(3)(C(6)H(5)N(3))]·H(2)O, contains two crystallographically independent cations, two anions and two water molecules. The structure has been reported previously [Zhang, Li, Wang, Xie, Wang & Shen (2004 ▶). Acta Cryst E60, m498–m500] a...
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2007
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914941/ https://www.ncbi.nlm.nih.gov/pubmed/21200629 http://dx.doi.org/10.1107/S1600536807063131 |
| Sumario: | The asymmetric unit of the title compound, (C(6)H(6)N(3))[CoCl(3)(C(6)H(5)N(3))]·H(2)O, contains two crystallographically independent cations, two anions and two water molecules. The structure has been reported previously [Zhang, Li, Wang, Xie, Wang & Shen (2004 ▶). Acta Cryst E60, m498–m500] as a neutral cobalt(III) complex accompanied by unprotonated benzotriazole molecules and here has been redetermined as an anionic cobalt(II) complex accompanied by protonated benzotriazole cations. For both complex anions, a tetrahedral CoNCl(3) geometry arises. A network of N—H⋯O, N—H⋯Cl, O—H⋯O and O—H⋯Cl hydrogen bonds helps to establish the packing. |
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