trans-Bis[2-(piperazin-1-yl)­ethan­amine]­bis­(saccharinato)cobalt(II)

In the centrosymmetric title complex, [Co(C(7)H(4)NO(3)S)(2)(C(6)H(15)N(3))(2)], the Co(II) ion is coordinated by two saccharinate (sac) anions and two neutral 2-piperazin-1-ylethanamine (ppzea) ligands, showing a distorted octa­hedral coordination. Sac is O-bonded via the carbonyl group, while ppze...

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Detalles Bibliográficos
Autores principales: Yilmaz, Veysel T., Guney, Serkan, Kazak, Canan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914942/
https://www.ncbi.nlm.nih.gov/pubmed/21200630
http://dx.doi.org/10.1107/S1600536807062745
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author Yilmaz, Veysel T.
Guney, Serkan
Kazak, Canan
author_facet Yilmaz, Veysel T.
Guney, Serkan
Kazak, Canan
author_sort Yilmaz, Veysel T.
collection PubMed
description In the centrosymmetric title complex, [Co(C(7)H(4)NO(3)S)(2)(C(6)H(15)N(3))(2)], the Co(II) ion is coordinated by two saccharinate (sac) anions and two neutral 2-piperazin-1-ylethanamine (ppzea) ligands, showing a distorted octa­hedral coordination. Sac is O-bonded via the carbonyl group, while ppzea acts as an N,N′-bidentate chelating ligand. The mol­ecules are connected by N—H⋯N and N—H⋯O hydrogen bonds, forming a linear chain running parallel to the crystallographic a axis. The compound is isostructural with the reported Ni, Zn, and Cd analogues.
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spelling pubmed-29149422010-12-30 trans-Bis[2-(piperazin-1-yl)­ethan­amine]­bis­(saccharinato)cobalt(II) Yilmaz, Veysel T. Guney, Serkan Kazak, Canan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title complex, [Co(C(7)H(4)NO(3)S)(2)(C(6)H(15)N(3))(2)], the Co(II) ion is coordinated by two saccharinate (sac) anions and two neutral 2-piperazin-1-ylethanamine (ppzea) ligands, showing a distorted octa­hedral coordination. Sac is O-bonded via the carbonyl group, while ppzea acts as an N,N′-bidentate chelating ligand. The mol­ecules are connected by N—H⋯N and N—H⋯O hydrogen bonds, forming a linear chain running parallel to the crystallographic a axis. The compound is isostructural with the reported Ni, Zn, and Cd analogues. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914942/ /pubmed/21200630 http://dx.doi.org/10.1107/S1600536807062745 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Yilmaz, Veysel T.
Guney, Serkan
Kazak, Canan
trans-Bis[2-(piperazin-1-yl)­ethan­amine]­bis­(saccharinato)cobalt(II)
title trans-Bis[2-(piperazin-1-yl)­ethan­amine]­bis­(saccharinato)cobalt(II)
title_full trans-Bis[2-(piperazin-1-yl)­ethan­amine]­bis­(saccharinato)cobalt(II)
title_fullStr trans-Bis[2-(piperazin-1-yl)­ethan­amine]­bis­(saccharinato)cobalt(II)
title_full_unstemmed trans-Bis[2-(piperazin-1-yl)­ethan­amine]­bis­(saccharinato)cobalt(II)
title_short trans-Bis[2-(piperazin-1-yl)­ethan­amine]­bis­(saccharinato)cobalt(II)
title_sort trans-bis[2-(piperazin-1-yl)­ethan­amine]­bis­(saccharinato)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914942/
https://www.ncbi.nlm.nih.gov/pubmed/21200630
http://dx.doi.org/10.1107/S1600536807062745
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AT guneyserkan transbis2piperazin1ylethanaminebissaccharinatocobaltii
AT kazakcanan transbis2piperazin1ylethanaminebissaccharinatocobaltii

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