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catena-Poly[[[triaqua­copper(II)]-μ(2)-pyrazine-2,3-dicarboxyl­ato] monohydrate]

The Cu atom in the title complex, {[Cu(C(6)H(2)N(2)O(4))(H(2)O)(3)]·H(2)O}(n) or {[Cu(L)(H(2)O)(3)]·H(2)O}(n) (L is pyrazine-2,3-dicarbox­yl­ate), displays octa­hedral coordination formed by the ligand L and three coordinated water mol­ecules. The ligand L is tridentate, with one N atom of the pyraz...

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Detalles Bibliográficos
Autores principales: Wu, Wei-Ping, Zeng, Feng-Chun, Wu, Yu, Peng, Jian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914943/
https://www.ncbi.nlm.nih.gov/pubmed/21200632
http://dx.doi.org/10.1107/S1600536807062800
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author Wu, Wei-Ping
Zeng, Feng-Chun
Wu, Yu
Peng, Jian
author_facet Wu, Wei-Ping
Zeng, Feng-Chun
Wu, Yu
Peng, Jian
author_sort Wu, Wei-Ping
collection PubMed
description The Cu atom in the title complex, {[Cu(C(6)H(2)N(2)O(4))(H(2)O)(3)]·H(2)O}(n) or {[Cu(L)(H(2)O)(3)]·H(2)O}(n) (L is pyrazine-2,3-dicarbox­yl­ate), displays octa­hedral coordination formed by the ligand L and three coordinated water mol­ecules. The ligand L is tridentate, with one N atom of the pyrazine ring and one O atom of one carboxyl­ate group forming a chelate ring, whereas one O atom from the second carboxyl­ate group is coordinated to another Cu atom. The ligand L links mol­ecules to form an infinite chain parallel to the [101] direction. The chains are further linked through O—H⋯O and O—H⋯N hydrogen bonds involving the water mol­ecules to build up a three-dimensional network.
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spelling pubmed-29149432010-12-30 catena-Poly[[[triaqua­copper(II)]-μ(2)-pyrazine-2,3-dicarboxyl­ato] monohydrate] Wu, Wei-Ping Zeng, Feng-Chun Wu, Yu Peng, Jian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu atom in the title complex, {[Cu(C(6)H(2)N(2)O(4))(H(2)O)(3)]·H(2)O}(n) or {[Cu(L)(H(2)O)(3)]·H(2)O}(n) (L is pyrazine-2,3-dicarbox­yl­ate), displays octa­hedral coordination formed by the ligand L and three coordinated water mol­ecules. The ligand L is tridentate, with one N atom of the pyrazine ring and one O atom of one carboxyl­ate group forming a chelate ring, whereas one O atom from the second carboxyl­ate group is coordinated to another Cu atom. The ligand L links mol­ecules to form an infinite chain parallel to the [101] direction. The chains are further linked through O—H⋯O and O—H⋯N hydrogen bonds involving the water mol­ecules to build up a three-dimensional network. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914943/ /pubmed/21200632 http://dx.doi.org/10.1107/S1600536807062800 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Wu, Wei-Ping
Zeng, Feng-Chun
Wu, Yu
Peng, Jian
catena-Poly[[[triaqua­copper(II)]-μ(2)-pyrazine-2,3-dicarboxyl­ato] monohydrate]
title catena-Poly[[[triaqua­copper(II)]-μ(2)-pyrazine-2,3-dicarboxyl­ato] monohydrate]
title_full catena-Poly[[[triaqua­copper(II)]-μ(2)-pyrazine-2,3-dicarboxyl­ato] monohydrate]
title_fullStr catena-Poly[[[triaqua­copper(II)]-μ(2)-pyrazine-2,3-dicarboxyl­ato] monohydrate]
title_full_unstemmed catena-Poly[[[triaqua­copper(II)]-μ(2)-pyrazine-2,3-dicarboxyl­ato] monohydrate]
title_short catena-Poly[[[triaqua­copper(II)]-μ(2)-pyrazine-2,3-dicarboxyl­ato] monohydrate]
title_sort catena-poly[[[triaqua­copper(ii)]-μ(2)-pyrazine-2,3-dicarboxyl­ato] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914943/
https://www.ncbi.nlm.nih.gov/pubmed/21200632
http://dx.doi.org/10.1107/S1600536807062800
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