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catena-Poly[[[triaquacopper(II)]-μ(2)-pyrazine-2,3-dicarboxylato] monohydrate]
The Cu atom in the title complex, {[Cu(C(6)H(2)N(2)O(4))(H(2)O)(3)]·H(2)O}(n) or {[Cu(L)(H(2)O)(3)]·H(2)O}(n) (L is pyrazine-2,3-dicarboxylate), displays octahedral coordination formed by the ligand L and three coordinated water molecules. The ligand L is tridentate, with one N atom of the pyraz...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914943/ https://www.ncbi.nlm.nih.gov/pubmed/21200632 http://dx.doi.org/10.1107/S1600536807062800 |
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author | Wu, Wei-Ping Zeng, Feng-Chun Wu, Yu Peng, Jian |
author_facet | Wu, Wei-Ping Zeng, Feng-Chun Wu, Yu Peng, Jian |
author_sort | Wu, Wei-Ping |
collection | PubMed |
description | The Cu atom in the title complex, {[Cu(C(6)H(2)N(2)O(4))(H(2)O)(3)]·H(2)O}(n) or {[Cu(L)(H(2)O)(3)]·H(2)O}(n) (L is pyrazine-2,3-dicarboxylate), displays octahedral coordination formed by the ligand L and three coordinated water molecules. The ligand L is tridentate, with one N atom of the pyrazine ring and one O atom of one carboxylate group forming a chelate ring, whereas one O atom from the second carboxylate group is coordinated to another Cu atom. The ligand L links molecules to form an infinite chain parallel to the [101] direction. The chains are further linked through O—H⋯O and O—H⋯N hydrogen bonds involving the water molecules to build up a three-dimensional network. |
format | Text |
id | pubmed-2914943 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29149432010-12-30 catena-Poly[[[triaquacopper(II)]-μ(2)-pyrazine-2,3-dicarboxylato] monohydrate] Wu, Wei-Ping Zeng, Feng-Chun Wu, Yu Peng, Jian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu atom in the title complex, {[Cu(C(6)H(2)N(2)O(4))(H(2)O)(3)]·H(2)O}(n) or {[Cu(L)(H(2)O)(3)]·H(2)O}(n) (L is pyrazine-2,3-dicarboxylate), displays octahedral coordination formed by the ligand L and three coordinated water molecules. The ligand L is tridentate, with one N atom of the pyrazine ring and one O atom of one carboxylate group forming a chelate ring, whereas one O atom from the second carboxylate group is coordinated to another Cu atom. The ligand L links molecules to form an infinite chain parallel to the [101] direction. The chains are further linked through O—H⋯O and O—H⋯N hydrogen bonds involving the water molecules to build up a three-dimensional network. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914943/ /pubmed/21200632 http://dx.doi.org/10.1107/S1600536807062800 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Wu, Wei-Ping Zeng, Feng-Chun Wu, Yu Peng, Jian catena-Poly[[[triaquacopper(II)]-μ(2)-pyrazine-2,3-dicarboxylato] monohydrate] |
title |
catena-Poly[[[triaquacopper(II)]-μ(2)-pyrazine-2,3-dicarboxylato] monohydrate] |
title_full |
catena-Poly[[[triaquacopper(II)]-μ(2)-pyrazine-2,3-dicarboxylato] monohydrate] |
title_fullStr |
catena-Poly[[[triaquacopper(II)]-μ(2)-pyrazine-2,3-dicarboxylato] monohydrate] |
title_full_unstemmed |
catena-Poly[[[triaquacopper(II)]-μ(2)-pyrazine-2,3-dicarboxylato] monohydrate] |
title_short |
catena-Poly[[[triaquacopper(II)]-μ(2)-pyrazine-2,3-dicarboxylato] monohydrate] |
title_sort | catena-poly[[[triaquacopper(ii)]-μ(2)-pyrazine-2,3-dicarboxylato] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914943/ https://www.ncbi.nlm.nih.gov/pubmed/21200632 http://dx.doi.org/10.1107/S1600536807062800 |
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