Bis(isopropyl­ammonium) tetra­sulfido­molybdate(VI)

The title compound, (C(3)H(10)N)(2)[MoS(4)], was synthesized by passing a rapid stream of H(2)S into an aqueous isopropyl­amine solution of molybdic acid. The title compound is isotypic with the corresponding W analogue (C(3)H(10)N)(2)[WS(4)]; its structure consists of a slightly distorted tetra­hed...

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Detalles Bibliográficos
Autores principales: Srinivasan, Bikshandarkoil R., Näther, Christian, Naik, Ashish R., Bensch, Wolfgang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914947/
https://www.ncbi.nlm.nih.gov/pubmed/21200636
http://dx.doi.org/10.1107/S1600536807063337
Descripción
Sumario:The title compound, (C(3)H(10)N)(2)[MoS(4)], was synthesized by passing a rapid stream of H(2)S into an aqueous isopropyl­amine solution of molybdic acid. The title compound is isotypic with the corresponding W analogue (C(3)H(10)N)(2)[WS(4)]; its structure consists of a slightly distorted tetra­hedral [MoS(4)](2−) dianion and two crystallographically independent isopropyl­ammonium cations, with all atoms located in general positions. The cations and anion are linked by weak N—H⋯S and C—H⋯S inter­actions, the strength and number of which can explain the observed Mo—S bond distances.

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