Dichlorido[1-(1-naphthyl­meth­yl)-3-(2-pyrid­yl)-1H-pyrazole-κ(2) N (2),N (3)]palladium(II)

In the title compound, [PdCl(2)(C(19)H(15)N(3))], the Pd(II) centre is four-coordinated by two N-atom donors from one 1-[3-(2-pyrid­yl)pyrazol-1-ylmeth­yl]naphthalene (L) ligand and by two Cl atoms in a distorted square-planar coordination geometry. In the crystal structure, adjacent Pd(II) mononucl...

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Detalles Bibliográficos
Autores principales: Liu, Chun-Sen, Sun, Guang-Hui, Guo, Liang-Qi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914949/
https://www.ncbi.nlm.nih.gov/pubmed/21200638
http://dx.doi.org/10.1107/S1600536807062927
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author Liu, Chun-Sen
Sun, Guang-Hui
Guo, Liang-Qi
author_facet Liu, Chun-Sen
Sun, Guang-Hui
Guo, Liang-Qi
author_sort Liu, Chun-Sen
collection PubMed
description In the title compound, [PdCl(2)(C(19)H(15)N(3))], the Pd(II) centre is four-coordinated by two N-atom donors from one 1-[3-(2-pyrid­yl)pyrazol-1-ylmeth­yl]naphthalene (L) ligand and by two Cl atoms in a distorted square-planar coordination geometry. In the crystal structure, adjacent Pd(II) mononuclear units form inter­molecular C—H⋯π inter­actions involving the benzene and pyridine rings of different L ligands and π–π stacking inter­actions between the pyrazolyl-pyridine and naphthalene rings of neighbouring L ligands, with a centroid–centroid separation of 3.522 (1) Å.
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spelling pubmed-29149492010-12-30 Dichlorido[1-(1-naphthyl­meth­yl)-3-(2-pyrid­yl)-1H-pyrazole-κ(2) N (2),N (3)]palladium(II) Liu, Chun-Sen Sun, Guang-Hui Guo, Liang-Qi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdCl(2)(C(19)H(15)N(3))], the Pd(II) centre is four-coordinated by two N-atom donors from one 1-[3-(2-pyrid­yl)pyrazol-1-ylmeth­yl]naphthalene (L) ligand and by two Cl atoms in a distorted square-planar coordination geometry. In the crystal structure, adjacent Pd(II) mononuclear units form inter­molecular C—H⋯π inter­actions involving the benzene and pyridine rings of different L ligands and π–π stacking inter­actions between the pyrazolyl-pyridine and naphthalene rings of neighbouring L ligands, with a centroid–centroid separation of 3.522 (1) Å. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914949/ /pubmed/21200638 http://dx.doi.org/10.1107/S1600536807062927 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Liu, Chun-Sen
Sun, Guang-Hui
Guo, Liang-Qi
Dichlorido[1-(1-naphthyl­meth­yl)-3-(2-pyrid­yl)-1H-pyrazole-κ(2) N (2),N (3)]palladium(II)
title Dichlorido[1-(1-naphthyl­meth­yl)-3-(2-pyrid­yl)-1H-pyrazole-κ(2) N (2),N (3)]palladium(II)
title_full Dichlorido[1-(1-naphthyl­meth­yl)-3-(2-pyrid­yl)-1H-pyrazole-κ(2) N (2),N (3)]palladium(II)
title_fullStr Dichlorido[1-(1-naphthyl­meth­yl)-3-(2-pyrid­yl)-1H-pyrazole-κ(2) N (2),N (3)]palladium(II)
title_full_unstemmed Dichlorido[1-(1-naphthyl­meth­yl)-3-(2-pyrid­yl)-1H-pyrazole-κ(2) N (2),N (3)]palladium(II)
title_short Dichlorido[1-(1-naphthyl­meth­yl)-3-(2-pyrid­yl)-1H-pyrazole-κ(2) N (2),N (3)]palladium(II)
title_sort dichlorido[1-(1-naphthyl­meth­yl)-3-(2-pyrid­yl)-1h-pyrazole-κ(2) n (2),n (3)]palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914949/
https://www.ncbi.nlm.nih.gov/pubmed/21200638
http://dx.doi.org/10.1107/S1600536807062927
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AT guoliangqi dichlorido11naphthylmethyl32pyridyl1hpyrazolek2n2n3palladiumii

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