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Poly[[tetraaquabis[μ(3)-1-ethyl-6-fluoro-4-oxo-7-(piperazinium-1-yl)-1H-quinoline-3-carboxylato]dinickel(II)] hydroxide nitrate]
In the title compound, [Ni(2)(C(16)H(18)FN(3)O(3))(2)(H(2)O)(4)](OH)(NO(3)), the cationic [Ni(2)(C(16)H(18)FN(3)O(3))(2)(H(2)O)(4)](2+) building units are linked through Ni–O(carboxylate) and Ni—N(amino) bridges into a layer structure. The two independent nickel atoms lie on inversion centres: one...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2007
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914950/ https://www.ncbi.nlm.nih.gov/pubmed/21200640 http://dx.doi.org/10.1107/S1600536807062885 |
| _version_ | 1782184823835590656 |
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| author | Song, Wen-Dong Wan, Yi-Ling Hong, Peng-Zhi Ng, Seik Weng |
| author_facet | Song, Wen-Dong Wan, Yi-Ling Hong, Peng-Zhi Ng, Seik Weng |
| author_sort | Song, Wen-Dong |
| collection | PubMed |
| description | In the title compound, [Ni(2)(C(16)H(18)FN(3)O(3))(2)(H(2)O)(4)](OH)(NO(3)), the cationic [Ni(2)(C(16)H(18)FN(3)O(3))(2)(H(2)O)(4)](2+) building units are linked through Ni–O(carboxylate) and Ni—N(amino) bridges into a layer structure. The two independent nickel atoms lie on inversion centres: one adopts an NiO(6) octahedral geometry, the other a trans-NiN(2)O(4) octahedral arrangement. The charge-balancing hydroxide and nitrate ions are of half site occupancy each. A network of O—H⋯O and N—H⋯O hydrogen bonds helps to establish the packing. |
| format | Text |
| id | pubmed-2914950 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29149502010-12-30 Poly[[tetraaquabis[μ(3)-1-ethyl-6-fluoro-4-oxo-7-(piperazinium-1-yl)-1H-quinoline-3-carboxylato]dinickel(II)] hydroxide nitrate] Song, Wen-Dong Wan, Yi-Ling Hong, Peng-Zhi Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(2)(C(16)H(18)FN(3)O(3))(2)(H(2)O)(4)](OH)(NO(3)), the cationic [Ni(2)(C(16)H(18)FN(3)O(3))(2)(H(2)O)(4)](2+) building units are linked through Ni–O(carboxylate) and Ni—N(amino) bridges into a layer structure. The two independent nickel atoms lie on inversion centres: one adopts an NiO(6) octahedral geometry, the other a trans-NiN(2)O(4) octahedral arrangement. The charge-balancing hydroxide and nitrate ions are of half site occupancy each. A network of O—H⋯O and N—H⋯O hydrogen bonds helps to establish the packing. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914950/ /pubmed/21200640 http://dx.doi.org/10.1107/S1600536807062885 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
| spellingShingle | Metal-Organic Papers Song, Wen-Dong Wan, Yi-Ling Hong, Peng-Zhi Ng, Seik Weng Poly[[tetraaquabis[μ(3)-1-ethyl-6-fluoro-4-oxo-7-(piperazinium-1-yl)-1H-quinoline-3-carboxylato]dinickel(II)] hydroxide nitrate] |
| title | Poly[[tetraaquabis[μ(3)-1-ethyl-6-fluoro-4-oxo-7-(piperazinium-1-yl)-1H-quinoline-3-carboxylato]dinickel(II)] hydroxide nitrate] |
| title_full | Poly[[tetraaquabis[μ(3)-1-ethyl-6-fluoro-4-oxo-7-(piperazinium-1-yl)-1H-quinoline-3-carboxylato]dinickel(II)] hydroxide nitrate] |
| title_fullStr | Poly[[tetraaquabis[μ(3)-1-ethyl-6-fluoro-4-oxo-7-(piperazinium-1-yl)-1H-quinoline-3-carboxylato]dinickel(II)] hydroxide nitrate] |
| title_full_unstemmed | Poly[[tetraaquabis[μ(3)-1-ethyl-6-fluoro-4-oxo-7-(piperazinium-1-yl)-1H-quinoline-3-carboxylato]dinickel(II)] hydroxide nitrate] |
| title_short | Poly[[tetraaquabis[μ(3)-1-ethyl-6-fluoro-4-oxo-7-(piperazinium-1-yl)-1H-quinoline-3-carboxylato]dinickel(II)] hydroxide nitrate] |
| title_sort | poly[[tetraaquabis[μ(3)-1-ethyl-6-fluoro-4-oxo-7-(piperazinium-1-yl)-1h-quinoline-3-carboxylato]dinickel(ii)] hydroxide nitrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914950/ https://www.ncbi.nlm.nih.gov/pubmed/21200640 http://dx.doi.org/10.1107/S1600536807062885 |
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