Chlorido(1,10-phenanthroline)(1H-1,2,4-triazole-3-carboxyl­ato)copper(II)

The title complex, [Cu(C(3)H(2)N(3)O(2))Cl(C(12)H(8)N(2))], crystallizes with two independent mol­ecules in the asymmetric unit. Each Cu(II) atom is coordinated by an N atom and an O atom from the bidentate 1H-1,2,4-triazole-3-carboxyl­ate ligand, two N atoms from the 1,10-phenanthroline ligand, and...

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Detalles Bibliográficos
Autores principales: Zhu, Jie, Yin, Xian-Hong, Feng, Yu, Zhang, Shan-Shan, Zhao, Kai, Lin, Cui-Wu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914951/
https://www.ncbi.nlm.nih.gov/pubmed/21200641
http://dx.doi.org/10.1107/S160053680706299X
Descripción
Sumario:The title complex, [Cu(C(3)H(2)N(3)O(2))Cl(C(12)H(8)N(2))], crystallizes with two independent mol­ecules in the asymmetric unit. Each Cu(II) atom is coordinated by an N atom and an O atom from the bidentate 1H-1,2,4-triazole-3-carboxyl­ate ligand, two N atoms from the 1,10-phenanthroline ligand, and the Cl atom. The coordination geometry is based on a ClN(3)O square pyramid. In the crystal structure, the mol­ecules are linked by inter­molecular N—H⋯O hydrogen bonds.

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