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[(6-Methyl-2-pyridylmethyl)(2-pyridylmethyl)amine][(2-pyridylmethyl)amine]copper(II) bis(perchlorate)
The title compound, [Cu(C(6)H(8)N(2))(C(13)H(15)N(3))](ClO(4))(2), is a mixed ligand complex with the Cu(II) atom coordinated by (6-methyl-2-pyridylmethyl)(2-pyridylmethyl)amine, acting as a tridentate ligand, and 2-(2-aminomethyl)pyridine, as a bidentate ligand, leading to an N(5) square-pyrami...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914953/ https://www.ncbi.nlm.nih.gov/pubmed/21200643 http://dx.doi.org/10.1107/S1600536807062952 |
Sumario: | The title compound, [Cu(C(6)H(8)N(2))(C(13)H(15)N(3))](ClO(4))(2), is a mixed ligand complex with the Cu(II) atom coordinated by (6-methyl-2-pyridylmethyl)(2-pyridylmethyl)amine, acting as a tridentate ligand, and 2-(2-aminomethyl)pyridine, as a bidentate ligand, leading to an N(5) square-pyramidal geometry. The amine H atoms are involved in hydrogen bonding to the perchlorate O atoms and there are extensive but weak intermolecular C—H⋯O interactions in the crystal structure. The perchlorate ions are each disordered over two positions, with site occupancies of 0.601 (8):0.399 (8) and 0.659 (11):0.341 (11). |
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