Diazido­bis(2,2′-biimidazole)cobalt(II)

In the title compound, [Co(N(3))(2)(C(6)H(6)N(4))(2)], the Co(II) atom lies on a centre of inversion and is bonded to two azide ions and two bidentate 2,2′-biimidizole ligands, giving a slightly distorted octa­hedral CoN(6) coordination geometry. In the crystal structure, inter­molecular N—H⋯N hydro...

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Detalles Bibliográficos
Autores principales: Li, Sheng, Wang, Shou-Bin, Zhang, Fu-Li, Tang, Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914954/
https://www.ncbi.nlm.nih.gov/pubmed/21200644
http://dx.doi.org/10.1107/S1600536807062873
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author Li, Sheng
Wang, Shou-Bin
Zhang, Fu-Li
Tang, Kun
author_facet Li, Sheng
Wang, Shou-Bin
Zhang, Fu-Li
Tang, Kun
author_sort Li, Sheng
collection PubMed
description In the title compound, [Co(N(3))(2)(C(6)H(6)N(4))(2)], the Co(II) atom lies on a centre of inversion and is bonded to two azide ions and two bidentate 2,2′-biimidizole ligands, giving a slightly distorted octa­hedral CoN(6) coordination geometry. In the crystal structure, inter­molecular N—H⋯N hydrogen bonds exist between the 2,2′-biimidizole ligands and the azide ions, linking the complexes into sheets.
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spelling pubmed-29149542010-12-30 Diazido­bis(2,2′-biimidazole)cobalt(II) Li, Sheng Wang, Shou-Bin Zhang, Fu-Li Tang, Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(N(3))(2)(C(6)H(6)N(4))(2)], the Co(II) atom lies on a centre of inversion and is bonded to two azide ions and two bidentate 2,2′-biimidizole ligands, giving a slightly distorted octa­hedral CoN(6) coordination geometry. In the crystal structure, inter­molecular N—H⋯N hydrogen bonds exist between the 2,2′-biimidizole ligands and the azide ions, linking the complexes into sheets. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914954/ /pubmed/21200644 http://dx.doi.org/10.1107/S1600536807062873 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Li, Sheng
Wang, Shou-Bin
Zhang, Fu-Li
Tang, Kun
Diazido­bis(2,2′-biimidazole)cobalt(II)
title Diazido­bis(2,2′-biimidazole)cobalt(II)
title_full Diazido­bis(2,2′-biimidazole)cobalt(II)
title_fullStr Diazido­bis(2,2′-biimidazole)cobalt(II)
title_full_unstemmed Diazido­bis(2,2′-biimidazole)cobalt(II)
title_short Diazido­bis(2,2′-biimidazole)cobalt(II)
title_sort diazido­bis(2,2′-biimidazole)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914954/
https://www.ncbi.nlm.nih.gov/pubmed/21200644
http://dx.doi.org/10.1107/S1600536807062873
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AT wangshoubin diazidobis22biimidazolecobaltii
AT zhangfuli diazidobis22biimidazolecobaltii
AT tangkun diazidobis22biimidazolecobaltii

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