Diaqua­bis(pyrimidine-2-carboxylic acid-κ(2) N,O)cobalt(II) dichloride

In the title salt, [Co(C(5)H(4)N(2)O(2))(2)(H(2)O)(2)]Cl(2), the Co(II) ion is located on an inversion center. It is chelated by two neutral pyrimidine-2-carboxylic acid molecules and is coordinated by two water mol­ecules in an octa­hedral coordination geometry. The cations and anions are linked vi...

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Detalles Bibliográficos
Autores principales: Xu, Duan-Jun, Zhang, Bing-Yu, Yang, Qian, Nie, Jing-Jing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914955/
https://www.ncbi.nlm.nih.gov/pubmed/21200645
http://dx.doi.org/10.1107/S1600536807063258
Descripción
Sumario:In the title salt, [Co(C(5)H(4)N(2)O(2))(2)(H(2)O)(2)]Cl(2), the Co(II) ion is located on an inversion center. It is chelated by two neutral pyrimidine-2-carboxylic acid molecules and is coordinated by two water mol­ecules in an octa­hedral coordination geometry. The cations and anions are linked via O—H⋯Cl hydrogen bonds into a layer structure; an intra­molecular O—H⋯N hydrogen bond connects the carboxylic acid group to the pyrimidine N atom.

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