cis-Bis[2-(cyclo­propyl­imino­meth­yl)-6-methoxy­phenolato]bis­(thio­cyanato)cobalt(II)

In the title compound, [Co(NCS)(2)(C(11)H(13)NO(2))(2)], a mononuclear Schiff base cobalt(II) complex, the Co atom is six-coordinated by four O atoms from two Schiff base ligands, and by two N atoms from two thio­cyanate ligands, forming a distorted octa­hedral geometry. The central Co atom lies on...

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Detalles Bibliográficos
Autor principal: Wang, Shou-Xing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914956/
https://www.ncbi.nlm.nih.gov/pubmed/21200646
http://dx.doi.org/10.1107/S1600536807062186
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author Wang, Shou-Xing
author_facet Wang, Shou-Xing
author_sort Wang, Shou-Xing
collection PubMed
description In the title compound, [Co(NCS)(2)(C(11)H(13)NO(2))(2)], a mononuclear Schiff base cobalt(II) complex, the Co atom is six-coordinated by four O atoms from two Schiff base ligands, and by two N atoms from two thio­cyanate ligands, forming a distorted octa­hedral geometry. The central Co atom lies on a twofold rotation axis. An intramolecular N—H⋯O hydrogen bond is present.
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spelling pubmed-29149562010-12-30 cis-Bis[2-(cyclo­propyl­imino­meth­yl)-6-methoxy­phenolato]bis­(thio­cyanato)cobalt(II) Wang, Shou-Xing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(NCS)(2)(C(11)H(13)NO(2))(2)], a mononuclear Schiff base cobalt(II) complex, the Co atom is six-coordinated by four O atoms from two Schiff base ligands, and by two N atoms from two thio­cyanate ligands, forming a distorted octa­hedral geometry. The central Co atom lies on a twofold rotation axis. An intramolecular N—H⋯O hydrogen bond is present. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914956/ /pubmed/21200646 http://dx.doi.org/10.1107/S1600536807062186 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Wang, Shou-Xing
cis-Bis[2-(cyclo­propyl­imino­meth­yl)-6-methoxy­phenolato]bis­(thio­cyanato)cobalt(II)
title cis-Bis[2-(cyclo­propyl­imino­meth­yl)-6-methoxy­phenolato]bis­(thio­cyanato)cobalt(II)
title_full cis-Bis[2-(cyclo­propyl­imino­meth­yl)-6-methoxy­phenolato]bis­(thio­cyanato)cobalt(II)
title_fullStr cis-Bis[2-(cyclo­propyl­imino­meth­yl)-6-methoxy­phenolato]bis­(thio­cyanato)cobalt(II)
title_full_unstemmed cis-Bis[2-(cyclo­propyl­imino­meth­yl)-6-methoxy­phenolato]bis­(thio­cyanato)cobalt(II)
title_short cis-Bis[2-(cyclo­propyl­imino­meth­yl)-6-methoxy­phenolato]bis­(thio­cyanato)cobalt(II)
title_sort cis-bis[2-(cyclo­propyl­imino­meth­yl)-6-methoxy­phenolato]bis­(thio­cyanato)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914956/
https://www.ncbi.nlm.nih.gov/pubmed/21200646
http://dx.doi.org/10.1107/S1600536807062186
work_keys_str_mv AT wangshouxing cisbis2cyclopropyliminomethyl6methoxyphenolatobisthiocyanatocobaltii

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