Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)iron(II) dinitrate dihydrate

The title complex, [Fe(C(15)H(10)ClN(3))(2)](NO(3))(2)·2H(2)O, has a six-coordinate iron(II) center balanced by two nitrate anions. The Fe atom lies on a twofold rotation axis. The complex exhibits an octa­hedral coordination configuration, where the dihedral angle between the two planar tridentate...

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Detalles Bibliográficos
Autores principales: You, Wei, Yang, Xue-Yun, Yao, Cheng, Huang, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914957/
https://www.ncbi.nlm.nih.gov/pubmed/21200647
http://dx.doi.org/10.1107/S1600536807062836
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author You, Wei
Yang, Xue-Yun
Yao, Cheng
Huang, Wei
author_facet You, Wei
Yang, Xue-Yun
Yao, Cheng
Huang, Wei
author_sort You, Wei
collection PubMed
description The title complex, [Fe(C(15)H(10)ClN(3))(2)](NO(3))(2)·2H(2)O, has a six-coordinate iron(II) center balanced by two nitrate anions. The Fe atom lies on a twofold rotation axis. The complex exhibits an octa­hedral coordination configuration, where the dihedral angle between the two planar tridentate ligands is 92.4 (1)°. The crystal structure involves O—H⋯O hydrogen bonds.
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spelling pubmed-29149572010-12-30 Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)iron(II) dinitrate dihydrate You, Wei Yang, Xue-Yun Yao, Cheng Huang, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Fe(C(15)H(10)ClN(3))(2)](NO(3))(2)·2H(2)O, has a six-coordinate iron(II) center balanced by two nitrate anions. The Fe atom lies on a twofold rotation axis. The complex exhibits an octa­hedral coordination configuration, where the dihedral angle between the two planar tridentate ligands is 92.4 (1)°. The crystal structure involves O—H⋯O hydrogen bonds. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914957/ /pubmed/21200647 http://dx.doi.org/10.1107/S1600536807062836 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
You, Wei
Yang, Xue-Yun
Yao, Cheng
Huang, Wei
Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)iron(II) dinitrate dihydrate
title Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)iron(II) dinitrate dihydrate
title_full Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)iron(II) dinitrate dihydrate
title_fullStr Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)iron(II) dinitrate dihydrate
title_full_unstemmed Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)iron(II) dinitrate dihydrate
title_short Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)iron(II) dinitrate dihydrate
title_sort bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ(3) n,n′,n′′)iron(ii) dinitrate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914957/
https://www.ncbi.nlm.nih.gov/pubmed/21200647
http://dx.doi.org/10.1107/S1600536807062836
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