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Poly[[(μ(2)-2-amino-4,5-dimethybenzenesulfonato-κ(2) N:O)(μ(2)-2-methylpyrazine-κ(2) N:N′)silver(I)] monohydrate]
In the title compound, {[Ag(C(8)H(10)NO(3)S)(C(7)H(6)N(2))]·H(2)O}(n), each Ag(I) cation is four-coordinated by three N atoms from two different 2-methylpyrazine ligands and one –NH(2) group of a 2-amino-4,5-dimethybenzenesulfonate ligand, and by one sulfonate O atom, in a distorted tetrahedral c...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914958/ https://www.ncbi.nlm.nih.gov/pubmed/21200649 http://dx.doi.org/10.1107/S1600536807063672 |
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author | Dong, Xian-Wu Li, Yu-Jie |
author_facet | Dong, Xian-Wu Li, Yu-Jie |
author_sort | Dong, Xian-Wu |
collection | PubMed |
description | In the title compound, {[Ag(C(8)H(10)NO(3)S)(C(7)H(6)N(2))]·H(2)O}(n), each Ag(I) cation is four-coordinated by three N atoms from two different 2-methylpyrazine ligands and one –NH(2) group of a 2-amino-4,5-dimethybenzenesulfonate ligand, and by one sulfonate O atom, in a distorted tetrahedral coordination geometry. The Ag(I) centres are bridged by both types of ligands, forming a two-dimensional network. N—H⋯O hydrogen bonds and O⋯O interactions complete the structure. |
format | Text |
id | pubmed-2914958 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29149582010-12-30 Poly[[(μ(2)-2-amino-4,5-dimethybenzenesulfonato-κ(2) N:O)(μ(2)-2-methylpyrazine-κ(2) N:N′)silver(I)] monohydrate] Dong, Xian-Wu Li, Yu-Jie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Ag(C(8)H(10)NO(3)S)(C(7)H(6)N(2))]·H(2)O}(n), each Ag(I) cation is four-coordinated by three N atoms from two different 2-methylpyrazine ligands and one –NH(2) group of a 2-amino-4,5-dimethybenzenesulfonate ligand, and by one sulfonate O atom, in a distorted tetrahedral coordination geometry. The Ag(I) centres are bridged by both types of ligands, forming a two-dimensional network. N—H⋯O hydrogen bonds and O⋯O interactions complete the structure. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914958/ /pubmed/21200649 http://dx.doi.org/10.1107/S1600536807063672 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Dong, Xian-Wu Li, Yu-Jie Poly[[(μ(2)-2-amino-4,5-dimethybenzenesulfonato-κ(2) N:O)(μ(2)-2-methylpyrazine-κ(2) N:N′)silver(I)] monohydrate] |
title | Poly[[(μ(2)-2-amino-4,5-dimethybenzenesulfonato-κ(2)
N:O)(μ(2)-2-methylpyrazine-κ(2)
N:N′)silver(I)] monohydrate] |
title_full | Poly[[(μ(2)-2-amino-4,5-dimethybenzenesulfonato-κ(2)
N:O)(μ(2)-2-methylpyrazine-κ(2)
N:N′)silver(I)] monohydrate] |
title_fullStr | Poly[[(μ(2)-2-amino-4,5-dimethybenzenesulfonato-κ(2)
N:O)(μ(2)-2-methylpyrazine-κ(2)
N:N′)silver(I)] monohydrate] |
title_full_unstemmed | Poly[[(μ(2)-2-amino-4,5-dimethybenzenesulfonato-κ(2)
N:O)(μ(2)-2-methylpyrazine-κ(2)
N:N′)silver(I)] monohydrate] |
title_short | Poly[[(μ(2)-2-amino-4,5-dimethybenzenesulfonato-κ(2)
N:O)(μ(2)-2-methylpyrazine-κ(2)
N:N′)silver(I)] monohydrate] |
title_sort | poly[[(μ(2)-2-amino-4,5-dimethybenzenesulfonato-κ(2)
n:o)(μ(2)-2-methylpyrazine-κ(2)
n:n′)silver(i)] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914958/ https://www.ncbi.nlm.nih.gov/pubmed/21200649 http://dx.doi.org/10.1107/S1600536807063672 |
work_keys_str_mv | AT dongxianwu polym22amino45dimethybenzenesulfonatok2nom22methylpyrazinek2nnsilverimonohydrate AT liyujie polym22amino45dimethybenzenesulfonatok2nom22methylpyrazinek2nnsilverimonohydrate |