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Dibromido(di-2-pyridyl disulfide-κ(2) N,N′)zinc(II)
The molecular structure of the title compound, [ZnBr(2)(C(10)H(8)N(2)S(2))], contains a seven-membered chelate ring in which the zinc atom is coordinated by two bromide ions and by the two pyridyl N atoms of a single 2,2′-dipyridyldisulfide (dpds) ligand within a slightly distorted tetrahedron. As...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2007
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914960/ https://www.ncbi.nlm.nih.gov/pubmed/21200652 http://dx.doi.org/10.1107/S1600536807063556 |
| Sumario: | The molecular structure of the title compound, [ZnBr(2)(C(10)H(8)N(2)S(2))], contains a seven-membered chelate ring in which the zinc atom is coordinated by two bromide ions and by the two pyridyl N atoms of a single 2,2′-dipyridyldisulfide (dpds) ligand within a slightly distorted tetrahedron. As is usual for this type of complex, the disulfide group does not participate in zinc coordination. The chelate complexes are connected via weak intermolecular C—H⋯Br hydrogen bonding into chains, which extend in the [010] direction. |
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