Dibromido(di-2-pyridyl disulfide-κ(2) N,N′)zinc(II)

The molecular structure of the title compound, [ZnBr(2)(C(10)H(8)N(2)S(2))], contains a seven-membered chelate ring in which the zinc atom is coordinated by two bromide ions and by the two pyridyl N atoms of a single 2,2′-dipyridyldisulfide (dpds) ligand within a slightly distorted tetra­hedron. As...

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Detalles Bibliográficos
Autores principales: Wriedt, Mario, Jess, Inke, Näther, Christian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914960/
https://www.ncbi.nlm.nih.gov/pubmed/21200652
http://dx.doi.org/10.1107/S1600536807063556
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author Wriedt, Mario
Jess, Inke
Näther, Christian
author_facet Wriedt, Mario
Jess, Inke
Näther, Christian
author_sort Wriedt, Mario
collection PubMed
description The molecular structure of the title compound, [ZnBr(2)(C(10)H(8)N(2)S(2))], contains a seven-membered chelate ring in which the zinc atom is coordinated by two bromide ions and by the two pyridyl N atoms of a single 2,2′-dipyridyldisulfide (dpds) ligand within a slightly distorted tetra­hedron. As is usual for this type of complex, the disulfide group does not participate in zinc coordination. The chelate complexes are connected via weak inter­molecular C—H⋯Br hydrogen bonding into chains, which extend in the [010] direction.
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spelling pubmed-29149602010-12-30 Dibromido(di-2-pyridyl disulfide-κ(2) N,N′)zinc(II) Wriedt, Mario Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The molecular structure of the title compound, [ZnBr(2)(C(10)H(8)N(2)S(2))], contains a seven-membered chelate ring in which the zinc atom is coordinated by two bromide ions and by the two pyridyl N atoms of a single 2,2′-dipyridyldisulfide (dpds) ligand within a slightly distorted tetra­hedron. As is usual for this type of complex, the disulfide group does not participate in zinc coordination. The chelate complexes are connected via weak inter­molecular C—H⋯Br hydrogen bonding into chains, which extend in the [010] direction. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914960/ /pubmed/21200652 http://dx.doi.org/10.1107/S1600536807063556 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Wriedt, Mario
Jess, Inke
Näther, Christian
Dibromido(di-2-pyridyl disulfide-κ(2) N,N′)zinc(II)
title Dibromido(di-2-pyridyl disulfide-κ(2) N,N′)zinc(II)
title_full Dibromido(di-2-pyridyl disulfide-κ(2) N,N′)zinc(II)
title_fullStr Dibromido(di-2-pyridyl disulfide-κ(2) N,N′)zinc(II)
title_full_unstemmed Dibromido(di-2-pyridyl disulfide-κ(2) N,N′)zinc(II)
title_short Dibromido(di-2-pyridyl disulfide-κ(2) N,N′)zinc(II)
title_sort dibromido(di-2-pyridyl disulfide-κ(2) n,n′)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914960/
https://www.ncbi.nlm.nih.gov/pubmed/21200652
http://dx.doi.org/10.1107/S1600536807063556
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AT natherchristian dibromidodi2pyridyldisulfidek2nnzincii

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