Cargando…
Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato]nickel(II)–aqua[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinic acid]dithiocyanatonickel(II) (1/1)
In the title cocrystal, [Ni(C(11)H(10)N(3)O(2))(2)]·[Ni(NCS)(2)(C(11)H(11)N(3)O(2))(H(2)O)], both Ni(II) ions are in disorted octahedral coordination environments. One Ni(II) ion is coordinated by four N atoms and two O atoms from two tridentate 6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate (DPP) liga...
| Autores principales: | , , , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2007
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914961/ https://www.ncbi.nlm.nih.gov/pubmed/21200653 http://dx.doi.org/10.1107/S1600536807063957 |
| _version_ | 1782184826470662144 |
|---|---|
| author | Zhao, Kai Yin, Xian-Hong Lin, Cui-Wu Meng, Dong-Xu Wu, Fei-yan |
| author_facet | Zhao, Kai Yin, Xian-Hong Lin, Cui-Wu Meng, Dong-Xu Wu, Fei-yan |
| author_sort | Zhao, Kai |
| collection | PubMed |
| description | In the title cocrystal, [Ni(C(11)H(10)N(3)O(2))(2)]·[Ni(NCS)(2)(C(11)H(11)N(3)O(2))(H(2)O)], both Ni(II) ions are in disorted octahedral coordination environments. One Ni(II) ion is coordinated by four N atoms and two O atoms from two tridentate 6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate (DPP) ligands, while the other Ni(II) ion is coordinated by a tridentate 6-((3,5-dimethyl-1H-pyrazol-1-yl))picolinic acid (DPPH) ligand and by two N atoms and one O atom from two thiocyanate and one water ligand, respectively. In the crystal structure, molecules are linked by intermolecular O—H⋯O and O—H⋯S hydrogen bonds, forming extended chains along [010]. |
| format | Text |
| id | pubmed-2914961 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29149612010-12-30 Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato]nickel(II)–aqua[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinic acid]dithiocyanatonickel(II) (1/1) Zhao, Kai Yin, Xian-Hong Lin, Cui-Wu Meng, Dong-Xu Wu, Fei-yan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title cocrystal, [Ni(C(11)H(10)N(3)O(2))(2)]·[Ni(NCS)(2)(C(11)H(11)N(3)O(2))(H(2)O)], both Ni(II) ions are in disorted octahedral coordination environments. One Ni(II) ion is coordinated by four N atoms and two O atoms from two tridentate 6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate (DPP) ligands, while the other Ni(II) ion is coordinated by a tridentate 6-((3,5-dimethyl-1H-pyrazol-1-yl))picolinic acid (DPPH) ligand and by two N atoms and one O atom from two thiocyanate and one water ligand, respectively. In the crystal structure, molecules are linked by intermolecular O—H⋯O and O—H⋯S hydrogen bonds, forming extended chains along [010]. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914961/ /pubmed/21200653 http://dx.doi.org/10.1107/S1600536807063957 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
| spellingShingle | Metal-Organic Papers Zhao, Kai Yin, Xian-Hong Lin, Cui-Wu Meng, Dong-Xu Wu, Fei-yan Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato]nickel(II)–aqua[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinic acid]dithiocyanatonickel(II) (1/1) |
| title | Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato]nickel(II)–aqua[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinic acid]dithiocyanatonickel(II) (1/1) |
| title_full | Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato]nickel(II)–aqua[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinic acid]dithiocyanatonickel(II) (1/1) |
| title_fullStr | Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato]nickel(II)–aqua[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinic acid]dithiocyanatonickel(II) (1/1) |
| title_full_unstemmed | Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato]nickel(II)–aqua[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinic acid]dithiocyanatonickel(II) (1/1) |
| title_short | Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato]nickel(II)–aqua[6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinic acid]dithiocyanatonickel(II) (1/1) |
| title_sort | bis[6-(3,5-dimethyl-1h-pyrazol-1-yl)picolinato]nickel(ii)–aqua[6-(3,5-dimethyl-1h-pyrazol-1-yl)picolinic acid]dithiocyanatonickel(ii) (1/1) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914961/ https://www.ncbi.nlm.nih.gov/pubmed/21200653 http://dx.doi.org/10.1107/S1600536807063957 |
| work_keys_str_mv | AT zhaokai bis635dimethyl1hpyrazol1ylpicolinatonickeliiaqua635dimethyl1hpyrazol1ylpicolinicaciddithiocyanatonickelii11 AT yinxianhong bis635dimethyl1hpyrazol1ylpicolinatonickeliiaqua635dimethyl1hpyrazol1ylpicolinicaciddithiocyanatonickelii11 AT lincuiwu bis635dimethyl1hpyrazol1ylpicolinatonickeliiaqua635dimethyl1hpyrazol1ylpicolinicaciddithiocyanatonickelii11 AT mengdongxu bis635dimethyl1hpyrazol1ylpicolinatonickeliiaqua635dimethyl1hpyrazol1ylpicolinicaciddithiocyanatonickelii11 AT wufeiyan bis635dimethyl1hpyrazol1ylpicolinatonickeliiaqua635dimethyl1hpyrazol1ylpicolinicaciddithiocyanatonickelii11 |