Di-tert-butyl­chlorido(pyrrolidine-1-dithio­carboxyl­ato-κ(2) S,S′)tin(IV)

The title compound, [Sn(C(4)H(9))(2)(C(5)H(8)NS(2))Cl], contains two mol­ecules in the asymmetric unit, with similar conformations. In both mol­ecules, the Sn atom adopts a distorted trigonal-bipyramidal geometry arising from two C atoms, one Cl atom and two S atoms from the bidentate dithio­carbama...

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Detalles Bibliográficos
Autores principales: Li, Fahui, Li, Yantuan, Harrison, William T. A., Wang, Weijie, Feng, Yanping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914963/
https://www.ncbi.nlm.nih.gov/pubmed/21200655
http://dx.doi.org/10.1107/S1600536807064288
Descripción
Sumario:The title compound, [Sn(C(4)H(9))(2)(C(5)H(8)NS(2))Cl], contains two mol­ecules in the asymmetric unit, with similar conformations. In both mol­ecules, the Sn atom adopts a distorted trigonal-bipyramidal geometry arising from two C atoms, one Cl atom and two S atoms from the bidentate dithio­carbamate ligand, with one Sn—S bond much longer than the other. One C atom of the pyrrolidine ring is disordered equally over two sites.

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