Di-tert-butyl­chlorido(pyrrolidine-1-dithio­carboxyl­ato-κ(2) S,S′)tin(IV)

The title compound, [Sn(C(4)H(9))(2)(C(5)H(8)NS(2))Cl], contains two mol­ecules in the asymmetric unit, with similar conformations. In both mol­ecules, the Sn atom adopts a distorted trigonal-bipyramidal geometry arising from two C atoms, one Cl atom and two S atoms from the bidentate dithio­carbama...

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Detalles Bibliográficos
Autores principales: Li, Fahui, Li, Yantuan, Harrison, William T. A., Wang, Weijie, Feng, Yanping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914963/
https://www.ncbi.nlm.nih.gov/pubmed/21200655
http://dx.doi.org/10.1107/S1600536807064288
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author Li, Fahui
Li, Yantuan
Harrison, William T. A.
Wang, Weijie
Feng, Yanping
author_facet Li, Fahui
Li, Yantuan
Harrison, William T. A.
Wang, Weijie
Feng, Yanping
author_sort Li, Fahui
collection PubMed
description The title compound, [Sn(C(4)H(9))(2)(C(5)H(8)NS(2))Cl], contains two mol­ecules in the asymmetric unit, with similar conformations. In both mol­ecules, the Sn atom adopts a distorted trigonal-bipyramidal geometry arising from two C atoms, one Cl atom and two S atoms from the bidentate dithio­carbamate ligand, with one Sn—S bond much longer than the other. One C atom of the pyrrolidine ring is disordered equally over two sites.
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spelling pubmed-29149632010-12-30 Di-tert-butyl­chlorido(pyrrolidine-1-dithio­carboxyl­ato-κ(2) S,S′)tin(IV) Li, Fahui Li, Yantuan Harrison, William T. A. Wang, Weijie Feng, Yanping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(C(4)H(9))(2)(C(5)H(8)NS(2))Cl], contains two mol­ecules in the asymmetric unit, with similar conformations. In both mol­ecules, the Sn atom adopts a distorted trigonal-bipyramidal geometry arising from two C atoms, one Cl atom and two S atoms from the bidentate dithio­carbamate ligand, with one Sn—S bond much longer than the other. One C atom of the pyrrolidine ring is disordered equally over two sites. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914963/ /pubmed/21200655 http://dx.doi.org/10.1107/S1600536807064288 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Li, Fahui
Li, Yantuan
Harrison, William T. A.
Wang, Weijie
Feng, Yanping
Di-tert-butyl­chlorido(pyrrolidine-1-dithio­carboxyl­ato-κ(2) S,S′)tin(IV)
title Di-tert-butyl­chlorido(pyrrolidine-1-dithio­carboxyl­ato-κ(2) S,S′)tin(IV)
title_full Di-tert-butyl­chlorido(pyrrolidine-1-dithio­carboxyl­ato-κ(2) S,S′)tin(IV)
title_fullStr Di-tert-butyl­chlorido(pyrrolidine-1-dithio­carboxyl­ato-κ(2) S,S′)tin(IV)
title_full_unstemmed Di-tert-butyl­chlorido(pyrrolidine-1-dithio­carboxyl­ato-κ(2) S,S′)tin(IV)
title_short Di-tert-butyl­chlorido(pyrrolidine-1-dithio­carboxyl­ato-κ(2) S,S′)tin(IV)
title_sort di-tert-butyl­chlorido(pyrrolidine-1-dithio­carboxyl­ato-κ(2) s,s′)tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914963/
https://www.ncbi.nlm.nih.gov/pubmed/21200655
http://dx.doi.org/10.1107/S1600536807064288
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